(Ethoxycarbonylmethyl)triphenylphosphonium chloride
ALDRICH/02615 - technical, ≥90% (AT)
Synonym: (2-
CAS Number: 17577-28-5
Empirical Formula (Hill Notation): C22H22ClO2P
Molecular Weight: 384.84
EC Number: 241-548-2
MDL Number: MFCD00011746
Linear Formula: CH3CH2OCOCH2P(Cl)(C6H5)3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 02615-100G
| assay | ≥90% (AT) |
| grade | technical |
| InChI | 1S/C22H22O2P.ClH/c1-2-24- |
| InChI key | DJGHVEPNEJKZBF-UHFFFAOYSA |
| mp | 120-123 °C (dec.) |
| 120-123 °C (lit.) | |
| reaction suitability | reaction type: C-C Bond Formation |
| SMILES string | [Cl-].CCOC(=O)C[P+](c1ccc |
| storage temp. | 2-8°C |
| Application: | Reactant for: • Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression • Ring-opening reactions with Wittig reagents • Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation • Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions • Preparation of phosphonium derivatives of coumarin |
| Other Notes: | Starting material for preparing the Wittig-reagent |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P261 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | ≥90% (AT) |
| mp | 120-123 °C (dec.); 120-123 °C (lit.) |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352108 |