Dichlorophenylborane

ALDRICH/101346 - 97%

Synonym: NSC 93889; Phenylboron dichloride; Phenyldichloroborane

CAS Number: 873-51-8
Empirical Formula (Hill Notation): C₆H₅BCl₂
Molecular Weight: 158.82
MDL Number: MFCD00013612
Linear Formula: C₆H₅BCl₂
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-101346-1G	1 g	$53.30 1/EA		Add To Favorites
45-101346-5G	5 g	$117.00 1/EA		Add To Favorites
45-101346-25G	25 g	$299.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	97%
bp	66 °C/11 mmHg (lit.)
density	1.224 g/mL at 25 °C (lit.)
InChI	1S/C6H5BCl2/c8-7(9)6-4-2-1-3-5-6/h1-5H
InChI key	NCQDQONETMHUMY-UHFFFAOYSA-N
Quality Level	100
reaction suitability	reagent type: reductant
refractive index	n20/D 1.545 (lit.)
SMILES string	ClB(Cl)c1ccccc1

Application:	Catalyst for: • Antiproliferative macrolide and cell migration inhibitor lactimidomycin • Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions • Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives • Stereoselective alkylative ring opening of cyclic anhydrides • Cross-metathesis reaction of amino derivatives with olefins • Asymmetric acetate aldol reactions • The reaction of aryl aldehydes with styrene and (E)-β-methylstyrene
Application:	Dichlorophenylborane can be used as a catalyst for: • The synthesis of an antiproliferative macrolide and cell migration inhibitor lactimidomycin. • Enantioselective synthesis of polyketide segments using vinylogous Mukaiyama aldol reactions. • Enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives. • Stereoselective alkylative ring opening of cyclic anhydrides. • Cross-metathesis reaction of amino derivatives with olefins. • Asymmetric acetate aldol reactions.
Packaging:	1, 5, 25 g in glass bottle

Symbol	GHS02,GHS05
Signal word	Danger
Hazard statements	H225 - H314
Precautionary statements	P210 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-34-37
Safety Statements	16-26-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3

Purity	97%
bp	66 °C/11 mmHg (lit.)
Density	1.224 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.545 (lit.)
UNSPSC	12352002

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