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3-Bromothiophene

ALDRICH/106224 - 97%

Synonym: 3-Thienyl bromide

CAS Number: 872-31-1
Empirical Formula (Hill Notation): C4H3BrS
Molecular Weight: 163.04
EC Number: 212-821-3
MDL Number: MFCD00005464
Linear Formula: C4H3BrS
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-106224-5G 5 g
 $58.50
1/EA		 Add To Favorites
45-106224-25G 25 g
 $94.70
1/EA		 Add To Favorites
45-106224-100G 100 g
 $166.00
1/EA		 Add To Favorites

 

assay 97%
bp 150 °C (lit.)
density 1.74 g/mL at 25 °C (lit.)
InChI 1S/C4H3BrS/c5-4-1-2-6-3-4/h1-3H
InChI key XCMISAPCWHTVNG-UHFFFAOYSA-N
Quality Level 100 
refractive index n20/D 1.591 (lit.)
SMILES string Brc1ccsc1
Application: 3-Bromothiophene can be used as a reactant to synthesize:
• 3,3-Bithiophene via borylation followed by Suzuki coupling.
• 3-Alkylthiophenes by NiDPPP++ catalyzed cross-coupling with Grignard reagents.
• 3-Lithiothiophene by treating with n-butyllithium in hexane.
• Derivatives of thienylenic α, ω−diformyl−α−oligothiophenes.
• N-(2-(3-bromothiophen-2-yl)phenyl)methanesulfonamides by coupling at the 2-position with N-arylmethanesulfonamides, mediated by iodobenzene diacetate (178721).
Packaging: 5, 25, 100 g in glass bottle
Purity 97%
bp 150 °C (lit.)
Density 1.74 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.591 (lit.)
UNSPSC 12352100

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