2,2,2-Trifluoroacetophenone

ALDRICH/107840 - 99%

Synonym: α,α,α-Trifluoroacetophenone; Phenyl trifluoromethyl ketone

CAS Number: 434-45-7
Empirical Formula (Hill Notation): C₈H₅F₃O
Molecular Weight: 174.12
EC Number: 207-103-1
MDL Number: MFCD00000420
Linear Formula: CF₃COC₆H₅
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-107840-5G	5 g	$51.30 1/EAAdd To Favorites	Add To Favorites
45-107840-25G	25 g	$244.00 1/EAAdd To Favorites	Add To Favorites
45-107840-100G	100 g	$532.00 1/EAAdd To Favorites	Add To Favorites

assay	99%
bp	165-166 °C (lit.)
	46-48 °C/14 mmHg (lit.)
density	1.24 g/mL at 25 °C (lit.)
functional group	fluoro
	ketone
	phenyl
InChI	1S/C8H5F3O/c9-8(10,11)7(12)6-4-2-1-3-5-6/h1-5H
InChI key	KZJRKRQSDZGHEC-UHFFFAOYSA-N
Quality Level	200
refractive index	n20/D 1.458 (lit.)
SMILES string	FC(F)(F)C(=O)c1ccccc1

Application:	2,2,2-Trifluoroacetophenone was used in the synthesis of new fluorinated polymers, having high average molecular weight, high thermal stability and good film-forming properties.
General description:	2,2,2-Trifluoroacetophenone is the starting material for the synthesis of f 3-trifluoromethyl-3-phenyldiazirine. It undergoes asymmetric reduction with optically active Grignard reagent to form 2,2,2-trifluoro-1-phenylethanol. It undergoes condensation with biphenyl, terphenyl, a mixture of biphenyl with terphenyl, phenyl ether and diphenoxybenzophenone to form new aromatic 3F polymers. 2,2,2-trifluoroacetophenone is used as an organocatalyst for the oxidation of tertiary amines and azines to N-oxidesalkenes.
Packaging:	5, 25, 100 g in glass bottle

Symbol	GHS02,GHS07
Signal word	Warning
Hazard statements	H226 - H315 - H319 - H335
Precautionary statements	P210 - P302 + P352 - P305 + P351 + P338
Hazard Codes	Xi
Risk Statements	10-36/37/38
Safety Statements	26-36
RIDADR	UN1224 - class 3 - PG 3 - Ketones, liquid, n.o.s., HI: all
WGK Germany	WGK 3
Flash Point(F)	105.8 °F - closed cup
Flash Point(C)	41 °C - closed cup

Purity	99%
bp	165-166 °C (lit.); 46-48 °C/14 mmHg (lit.)
Density	1.24 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.458 (lit.)
UNSPSC	12352100