2-Methyl-2-propanethiol
ALDRICH/109207 - 99%
Synonym: tert-Butyl mercaptan; TBM
CAS Number: 75-66-1
Empirical Formula (Hill Notation): C4H10S
Molecular Weight: 90.19
EC Number: 200-890-2
MDL Number: MFCD00004857
Linear Formula: (CH3)3CSH
Product Type: Chemical
| assay | 99% |
| bp | 62-65 °C (lit.) |
| density | 0.8 g/mL at 25 °C (lit.) |
| InChI | 1S/C4H10S/c1-4(2,3)5/h5H, |
| InChI key | WMXCDAVJEZZYLT-UHFFFAOYSA |
| mp | -0.5 °C (lit.) |
| Quality Level | 100  |
| refractive index | n |
| SMILES string | CC(C)(C)S |
| solubility | alcohol: very soluble |
| diethyl ether: very soluble | |
| H2O: slightly soluble | |
| vapor density | 3.1 (vs air) |
| vapor pressure | 303.5 mmHg ( 37.7 °C) |
| Application: | 2-Methyl-2-propanethiol was used in reaction of 2-methyl-2-propanethiol on Mo(110) using temperature programmed reaction, high resolution electron enegy loss and X-ray photoelectron spectroscopies. It was used in the synthesis of chain-transfer agents for reversible addition-fragmentation chain-transfer copolymerization of vinylidene chloride and methyl acrylate. |
| General description: | 2-Methyl-2-propanethiol undergoes ring opening nucleophilic reaction with 3-isothiazolones and reaction kinetics studies suggested reaction was second order in thiol and third order overall. |
| Packaging: | 100, 500 mL in Sure/Seal™ |
| Packaging: | 2 L in Sure/Seal™ |
| Symbol |    GHS02,GHS07,GHS09 |
| Signal word | Danger |
| Hazard statements | H225 - H317 - H411 |
| Precautionary statements | P210 - P273 - P280 - P302 + P352 |
| Hazard Codes | F,Xn,N |
| Risk Statements | 11-43-51/53 |
| Safety Statements | 36/37-61 |
| RIDADR | UN 2347 3 / PGII |
| WGK Germany | WGK 3 |
| Flash Point(F) | -13.0 °F - closed cup |
| Flash Point(C) | < -25 °C - closed cup |
| Purity | 99% |
| bp | 62-65 °C (lit.) |
| mp | -0.5 °C (lit.) |
| Density | 0.8 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352100 |