Cyclopentadienylmolybdenum(II) tricarbonyl, dimer

ALDRICH/117609 - 98%

Synonym: Cyclopentadienyltricarbonylmolybdenum dimer; Hexacarbonylbis(η5 -cyclopentadienyl)dimolybdenum(I); Hexacarbonylbis(cyclopentadienyl)dimolybdenum

CAS Number: 12091-64-4
Empirical Formula (Hill Notation): C₁₆H₁₀Mo₂O₆
Molecular Weight: 490.13
EC Number: 235-156-0
MDL Number: MFCD00009947
Linear Formula: C₁₆H₁₀Mo₂O₆
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-117609-1G	1 g	$52.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	98%
form	solid
InChI	1S/2C5H5.6CO.2Mo/c21-2-4-5-3-1;61-2;;/h2*1-5H;;;;;;;;
InChI key	XCUPBPUEWLTPMQ-UHFFFAOYSA-N
mp	222 °C (dec.) (lit.)
Quality Level	100
reaction suitability	core: molybdenum
	reagent type: catalyst
SMILES string	[Mo][Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

Application:

Group 6 Carbonyl Complexes of N, O, P-ligands: Reviews the use of cyclopentadienyl molybdenum(II) dicarbonyl and tricarbonyl complexes as precursors for catalysts in olefin epoxidation. (SM Bruno, AA Valente, IS Gonçalves, 2023 ).
Monitoring Equilibrium Reaction Dynamics of a Nearly Barrierless Molecular Rotor: Describes using cyclopentadienylmolybdenum tricarbonyl dimer in ultrafast vibrational echo experiments to observe dynamic processes in barrierless molecular rotors. (IA Nilsen, DG Osborne, AM White, JM Anna, 2014 ).

Packaging:

1 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 + H312 + H332
Precautionary statements	P261 - P264 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312
Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	98%
mp	222 °C (dec.) (lit.)
UNSPSC	12352300

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