N-Hydroxyurethane
ALDRICH/119474
Synonym: N-
CAS Number: 589-41-3
Empirical Formula (Hill Notation): C3H7NO3
Molecular Weight: 105.09
EC Number: 209-648-0
MDL Number: MFCD00002108
Linear Formula: HONHCOOCH2CH3
Product Type: Chemical
bp | 113-116 °C/3 mmHg (lit.) |
InChI | 1S/C3H7NO3/c1-2-7-3(5)4-6 |
InChI key | VGEWEGHHYWGXGG-UHFFFAOYSA |
Quality Level | 200 |
refractive index | n |
SMILES string | CCOC(=O)NO |
storage temp. | −20°C |
Application: | N-Hydroxyurethane was used to synthesize N-methyl-O-benzylhydroxylamine and N-isopropyl-O-methylhydroxylamine. |
Application: | Reactant involved in: • Synthesis of molecules used for intermolecular Sharpless aminohydroxylation reactions • Intermolecular ortho-C-H amidation of anilides • Cinchona alkaloid-catalyzed asymmetric cycloaddition • Allylic arylation |
Biochem/physiol Actions: | N-Hydroxyurethane causes the chromosomal fragmentation at millimolar concentrations and cell toxicity in cultured normal human leukocytes. |
Packaging: | 5, 25 g in glass bottle |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 2 |
Flash Point(F) | 235.4 °F - closed cup |
Flash Point(C) | 113 °C - closed cup |
bp | 113-116 °C/3 mmHg (lit.) |
Refractive Index | n |
Storage Temp. | −20°C |
UNSPSC | 12352100 |