4-Chlorothiophenol
ALDRICH/125237 - 97%
Synonym: 4-Chlorobenzenethiol; 4-Chlorophenyl mercaptan
CAS Number: 106-54-7
Empirical Formula (Hill Notation): C6H5ClS
Molecular Weight: 144.62
EC Number: 203-408-9
MDL Number: MFCD00004847
Linear Formula: ClC6H4SH
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 125237-500G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 125237-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 125237-5G
| assay | 97% |
| bp | 205-207 °C (lit.) |
| form | solid |
| InChI | 1S/C6H5ClS/c7-5-1-3-6(8)4 |
| InChI key | VZXOZSQDJJNBRC-UHFFFAOYSA |
| mp | 49-51 °C (lit.) |
| Quality Level | 100  |
| SMILES string | Sc1ccc(Cl)cc1 |
| solubility | methanol: soluble |
| Application: | 4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups. |
| Application: | Reactant involved in: • Oxidation to disulfides using cobalt-salen catalysts and air oxidizing agents • Thiourea-catalyzed sulfa-Michael addition to acryloyloxazolidinones • Pummerer-type cyclization • C-H Activation and C-S cross-coupling with heterocycles • Allylic sulfenylation with allylic carbonates • Lewis acid-catalyzed electrophilic ring-opening reactions of 2-aryl-3,4-dihydropyrans |
| General description: | 4-Chlorothiophenol undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides. |
| Packaging: | 5, 100, 500 g in glass bottle |
| Symbol |   GHS05,GHS07 |
| Signal word | Danger |
| Hazard statements | H302 - H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 22-34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3261 8 / PGII |
| WGK Germany | WGK 3 |
| Purity | 97% |
| bp | 205-207 °C (lit.) |
| mp | 49-51 °C (lit.) |
| UNSPSC | 12352100 |