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2-Phenyl-1,3-dioxan-5-ol

ALDRICH/13468 - mixture of cis and trans, ≥97.0% (HPLC)

Synonym: 1,3-O-Benzylideneglycerol

CAS Number: 1708-40-3
Empirical Formula (Hill Notation): C10H12O3
Molecular Weight: 180.20
EC Number: 216-963-7
MDL Number: MFCD00047504
Linear Formula: C10H12O3
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-13468-1G-F 1 g
 $0.00
1/EA
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45-13468-5G-F 5 g
 $400.00
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assay ≥97.0% (HPLC)
form powder
functional group ether
  hydroxyl
  phenyl
InChI 1S/C10H12O3/c11-9-6-12-10(13-7-9)8-4-2-1-3-5-8/h1-5,9-11H,6-7H2
InChI key BWKDAAFSXYPQOS-UHFFFAOYSA-N
Quality Level 100 
SMILES string OC1COC(OC1)c2ccccc2
storage temp. 2-8°C
Application: 2-Phenyl-1,3-dioxan-5-ol can be used as a starting material in the synthesis of 5-benzyloxy1,3-dioxan-2-one (a carbonate of glycerol monomer). It undergoes ring-opening polymerization with ε-caprolactone in presence of tin(II) 2-ethylhexanoate (Sn(oct)2).
Application: 2-Phenyl-1,3-dioxan-5-ol was used as starting reagent in the synthesis of carbonate of glycerol monomer, 5-benzyloxy-1,3-dioxan-2-one which forms copolymers with ε-caprolactone.
General description: cis-2-phenyl-1,3-dioxan-5-ol reacts with triphenylphosphine-carbon tetrabromide to yield cis-4-bromomethyl-2-phenyl-1,3-dioxolan, its trans-diastereoisomer and trans-5-bromo-2-phenyl-1,3-dioxan.
Packaging: 1, 5 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) Not applicable
Flash Point(C) Not applicable
Purity ≥97.0% (HPLC)
Storage Temp. 2-8°C
UNSPSC 12352100

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