Di-tert-butyl azodicarboxylate
ALDRICH/135992 - 98%
Synonym: Bis(1,1-
CAS Number: 870-50-8
Empirical Formula (Hill Notation): C10H18N2O4
Molecular Weight: 230.26
EC Number: 212-796-9
MDL Number: MFCD00015001
Linear Formula: (CH3)3COCON=NCOOC(CH3)3
Product Type: Chemical
assay | 98% |
form | solid |
greener alternative category | Aligned ![]() |
greener alternative product characteristics | Catalysis Learn more about the Principles of Green Chemistry ![]() |
InChI | 1S/C10H18N2O4/c1-9(2,3)15 |
InChI key | QKSQWQOAUQFORH-VAWYXSNFSA |
mp | 89-92 °C (lit.) |
Quality Level | 200 ![]() |
SMILES string | CC(C)(C)OC(=O)N=NC(=O)O |
storage temp. | 2-8°C |
Application: | Co-oxidant in copper-catalyzed greener oxidation of alcohols under aerobic conditions. Modified Markó’s aerobic oxidation of alcohols under atmospheric pressure with air or molecular oxygen at room temperature ![]() ![]() |
Application: | Reactant for: • Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidati • Asymmetric Michael addition reactions • Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction • Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds • Barbier-type propargylation reactions • Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin • Asymmetric amination of glycine Schiff bases |
Application: | Reagent employed in the electrophilic amination of ß-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a |
Application: | Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst. |
General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. |
Packaging: | 5, 25 g in glass bottle |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98% |
mp | 89-92 °C (lit.) |
Storage Temp. | 2-8°C |
UNSPSC | 12352108 |