Di-tert-butyl azodicarboxylate
ALDRICH/135992 - 98%
Synonym: Bis(1,1-
CAS Number: 870-50-8
Empirical Formula (Hill Notation): C10H18N2O4
Molecular Weight: 230.26
EC Number: 212-796-9
MDL Number: MFCD00015001
Linear Formula: (CH3)3COCON=NCOOC(CH3)3
Product Type: Chemical
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.
| assay | 98% |
| form | solid |
| greener alternative category | Aligned  , |
| greener alternative product characteristics | Catalysis Learn more about the Principles of Green Chemistry . |
| InChI | 1S/C10H18N2O4/c1-9(2,3)15 |
| InChI key | QKSQWQOAUQFORH-VAWYXSNFSA |
| mp | 89-92 °C (lit.) |
| Quality Level | 200 |
| SMILES string | CC(C)(C)OC(=O)N=NC(=O)O |
| storage temp. | 2-8°C |
| sustainability | Greener Alternative Product |
| Application: | Co-oxidant in copper-catalyzed greener oxidation of alcohols under aerobic conditions. Modified Markó’s aerobic oxidation of alcohols under atmospheric pressure with air or molecular oxygen at room temperature  |
| Application: | Reactant for: • Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidati • Asymmetric Michael addition reactions • Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction • Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds • Barbier-type propargylation reactions • Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin • Asymmetric amination of glycine Schiff bases |
| Application: | Reagent employed in the electrophilic amination of ß-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a |
| Application: | Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst. |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Automate your Mitsunobu reactions with Synple Automated Synthesis Platform (SYNPLE-SC002 ) |
| Packaging: | 5, 25 g in glass bottle |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 98% |
| mp | 89-92 °C (lit.) |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352108 |