Di-tert-butyl azodicarboxylate

ALDRICH/135992 - 98%

Synonym: Bis(1,1-dimethylethyl)azodicarboxylate; DBAD; Di-tert-butyl azodiformate; NSC 109889

CAS Number: 870-50-8
Empirical Formula (Hill Notation): C₁₀H₁₈N₂O₄
Molecular Weight: 230.26
EC Number: 212-796-9
MDL Number: MFCD00015001
Linear Formula: (CH₃)₃COCON=NCOOC(CH₃)₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-135992-5G	5 g	$61.60 1/EAAdd To Favorites	Add To Favorites
45-135992-25G	25 g	$148.00 1/EAAdd To Favorites	Add To Favorites

assay	98%
form	solid
functional group	azo
greener alternative category	Aligned ,
greener alternative product characteristics	Catalysis Learn more about the Principles of Green Chemistry .
InChI	1S/C10H18N2O4/c1-9(2,3)15-7(13)11-12-8(14)16-10(4,5)6/h1-6H3/b12-11+
InChI key	QKSQWQOAUQFORH-VAWYXSNFSA-N
mp	89-92 °C (lit.)
Quality Level	200
SMILES string	CC(C)(C)OC(=O)N=NC(=O)OC(C)(C)C
storage temp.	2-8°C
sustainability	Greener Alternative Product

Application:	Co-oxidant in copper-catalyzed greener oxidation of alcohols under aerobic conditions. Modified Markó’s aerobic oxidation of alcohols under atmospheric pressure with air or molecular oxygen at room temperature
Application:	Reactant for: • Preparation of hexapeptide key fragments via stereoselective selenocyclization/oxidative deselenylation or hydrazination/cyclization reactions • Asymmetric Michael addition reactions • Preparation of dipeptidyl peptidase IV dependent water-soluble prodrugs via Mitsunobu reaction • Synthesis of pyrroloisoquinoline template via stereoselective N-acyliminium-mediated cyclization and enolate amination for synthesis of peptidomimetic compounds • Barbier-type propargylation reactions • Synthesis of bacterial peptide deformylase (PDF) inhibitor fumimycin • Asymmetric amination of glycine Schiff bases
Application:	Reagent employed in the electrophilic amination of ß-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole.
Application:	Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
General description:	We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Automate your Mitsunobu reactions with Synple Automated Synthesis Platform (SYNPLE-SC002 )
Packaging:	5, 25 g in glass bottle

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

Purity	98%
mp	89-92 °C (lit.)
Storage Temp.	2-8°C
UNSPSC	12352108