Phenyl benzoate

ALDRICH/142719 - 99%

Synonym: Benzoic acid phenyl ester

CAS Number: 93-99-2
Empirical Formula (Hill Notation): C₁₃H₁₀O₂
Molecular Weight: 198.22
EC Number: 202-293-2
MDL Number: MFCD00003072
Linear Formula: C₆H₅CO₂C₆H₅
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-142719-5G	5 g	$53.70 1/EAAdd To Favorites		Add To Favorites
45-142719-100G	100 g	$132.00 1/EAAdd To Favorites		Add To Favorites

assay	99%
bp	298-299 °C (lit.)
form	solid
functional group	ester
	phenoxy
	phenyl
InChI	1S/C13H10O2/c14-13(11-7-3-1-4-8-11)15-12-9-5-2-6-10-12/h1-10H
InChI key	FCJSHPDYVMKCHI-UHFFFAOYSA-N
mp	68-70 °C (lit.)
Quality Level	100
SMILES string	O=C(Oc1ccccc1)c2ccccc2
solubility	alcohol: freely soluble (hot)
	diethyl ether: slightly soluble
	water: insoluble

Application:	Phenyl benzoate was used in the synthesis of soluble polyimides using dianhydride/diamine derivatives.
General description:	Phenyl benzoate is a phenyl ester of benzoic acid. Crystal structure of phenyl benzoate has been determined from 844 microdensitometer-measured intensities. All bond lengths and angles were reported to be normal. Phenyl benzoate undergoes Fries rearrangement catalyzed by heteropoly acids to yield the acylated phenols and esters. Phenyl benzoate serves as a precursor that undergoes the intramolecular biaryl coupling reaction to produce the intermediate for the synthesis of (−)-steganone.
Packaging:	100 g in poly bottle
Packaging:	5 g in glass bottle

Symbol	GHS07
Signal word	Warning
Hazard statements	H302 - H315
Precautionary statements	P301 + P312 + P330 - P302 + P352
Hazard Codes	Xn
Risk Statements	22-38
Safety Statements	22-24/25
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable