1-(Trimethylsiloxy)cyclohexene

ALDRICH/144819 - 99%

Synonym: 1-Cyclohexenyloxytrimethylsilane; Cyclohexanone enol trimethylsilyl ether

CAS Number: 6651-36-1
Empirical Formula (Hill Notation): C₉H₁₈OSi
Molecular Weight: 170.32
EC Number: 229-675-1
MDL Number: MFCD00001541
Linear Formula: C₆H₉OSi(CH₃)₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-144819-5G	5 g	$129.00 1/EAAdd To Favorites	Add To Favorites

assay	99%
bp	64-65 °C/15 mmHg (lit.)
density	0.875 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C9H18OSi/c1-11(2,3)10-9-7-5-4-6-8-9/h7H,4-6,8H2,1-3H3
InChI key	SBEMOANGDSSPJY-UHFFFAOYSA-N
refractive index	n20/D 1.447 (lit.)
SMILES string	C[Si](C)(C)OC1=CCCCC1

Application:	1-(Trimethylsiloxy)cyclohexene was used in one-pot synthesis of Δ^1,9- octalone. It is intermediate to many complex compounds including natural products.
General description:	1-(Trimethylsiloxy)cyclohexene undergoes Michael addition reaction with methyl vinyl ketone in the presence of dibutyltin bis(triflate).
Packaging:	5, 25 g in glass bottle

Symbol	GHS02
Signal word	Warning
Hazard statements	H226
Risk Statements	10
RIDADR	UN 1993C 3 / PGIII
WGK Germany	WGK 3
Flash Point(F)	105.8 °F - closed cup
Flash Point(C)	41 °C - closed cup

Purity	99%
bp	64-65 °C/15 mmHg (lit.)
Density	0.875 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.447 (lit.)
UNSPSC	12352100