Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
ALDRICH/14694
Synonym: Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex
CAS Number: 35138-22-8
Empirical Formula (Hill Notation): C16H24BF4Rh
Molecular Weight: 406.07
MDL Number: MFCD00075045
Linear Formula: C16H24BF4Rh
Product Type: Chemical
composition | carbon content, 45.7-49.0% |
InChI | 1S/2C8H12.BF4.Rh/c2*1-2-4 |
InChI key | NBGSCPNNKGVTKU-QMDOQEJBSA |
mp | ~190 °C (dec.) |
Quality Level | 100 |
reaction suitability | core: rhodium |
reagent type: catalyst | |
SMILES string | [Rh+].F[B-](F)(F)F.C1CC=C |
Other Notes: | Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation; Hydrosilylation |
Packaging: | 100 mg in glass bottle |
Packaging: | Bottomless glass bottle. Contents are inside inserted fused cone. |
Symbol | GHS02,GHS05 |
Signal word | Danger |
Hazard statements | H228 - H314 |
Precautionary statements | P210 - P280 - P305 + P351 + P338 - P310 |
Hazard Codes | F |
Risk Statements | 11-34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 2921 4.1(8) / PGII |
WGK Germany | WGK 2 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
mp | ~190 °C (dec.) |
UNSPSC | 12352300 |