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9-Borabicyclo[3.3.1]nonane solution

ALDRICH/151076 - 0.5 M in THF

Synonym: 9-BBN

CAS Number: 280-64-8
Empirical Formula (Hill Notation): C8H15B
Molecular Weight: 122.02
MDL Number: MFCD00074742
Linear Formula: C8H15B
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-151076-4X25ML 25 mL
 $89.00
4/EA		 Add To Favorites
45-151076-100ML 100 mL
 $93.60
1/EA		 Add To Favorites
45-151076-800ML 800 mL
 $461.00
1/EA		 Add To Favorites
45-151076-8L 8 L
 $2300.00
1/EA		 Add To Favorites
45-151076-18L-KL 18 L
 $3750.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

concentration 0.5 M in THF
density 0.894 g/mL at 25 °C
form liquid
InChI 1S/C8H15B/c1-3-7-5-2-6-8(4-1)9-7/h7-9H,1-6H2/t7-,8+
InChI key FEJUGLKDZJDVFY-OCAPTIKFSA-N
Quality Level 100 
reaction suitability reagent type: reductant
SMILES string B1C2CCCC1CCC2
Application: Differentiation of symmetrical diols by reduction of the corresponding cyclic acetals with 9-BBN.
Application: Protecting group for alkenes†

Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides
• Intramolecular insertion of alkenes into palladium-nitrogen bonds
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids
Application: Selective hydroboration reduction reagent.
General description: 9-Borabicyclo[3.3.1]nonane is an organic compound, which is generally used as a hydroborating agent. It is thermally stable, less sensitive to oxygen and water when compared to other dialkyl boranes. It is commonly used to prepare aldehydes from alkynes.
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 4×25, 100, 800 mL in Sure/Seal™
Packaging: 8, 18 L in Kilo-Lab™
Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Packaging: View returnable container options .
Density 0.894 g/mL at 25 °C
UNSPSC 12352005

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