(−)-Bis[(S)-1-phenylethyl]amine hydrochloride
ALDRICH/15145 - ≥98.0% (AT)
Synonym: (−)-Bis[(S)-α-methylbenzyl]amine hydrochloride
CAS Number: 40648-92-8
Empirical Formula (Hill Notation): C16H19N · HCl
Molecular Weight: 261.79
MDL Number: MFCD00216671
Linear Formula: C16H19N · HCl
Product Type: Chemical
assay | ≥98.0% (AT) |
form | solid |
InChI | 1S/C16H19N.ClH/c1-13(15-9 |
InChI key | ZBQCLJZOKDRAOW-IODNYQNNSA |
mp | ~260 °C |
optical activity | [α]20/D −73±2°, c = 3% in ethanol |
Quality Level | 100 ![]() |
SMILES string | Cl.C[C@H](N[C@@H](C)c1ccc |
Application: | (−)-Bis[(S)-1-phenylethyl]amine hydrochloride can be used: • To prepare phosphoramidite (Feringa) ligand named (R)-2,2′-binaphthoyl-(S,S)-di-(1-phenylethyl)aminoylph • As a chiral amphiphilic cation to encapsulate polyoxometalates, which act as supramolecular assemblies employed in the asymmetric oxidation of sulfides. • As a chiral shift agent in the determination of enantiomeric purity of tris(tetrachlorobenzenedi |
Other Notes: | The corresponding chiral lithium amide is used as base for the enantioselective deprotonation of ketones. |
Packaging: | 5, 25 g in glass bottle |
Symbol | ![]() |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | ≥98.0% (AT) |
mp | ~260 °C |
UNSPSC | 12352116 |