Chloroform-d

ALDRICH/151823 - 99.8 atom % D

Synonym: Deuterochloroform

CAS Number: 865-49-6
Empirical Formula (Hill Notation): CCl₃D
Molecular Weight: 120.38
EC Number: 212-742-4
MDL Number: MFCD00000827
Linear Formula: CDCl₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-151823-10X0.6ML	0.6 mL	$38.40 10/EA	Add To Favorites
45-151823-10X0.75ML	0.75 mL	$40.20 10/EA	Add To Favorites
45-151823-10X1ML	1 mL	$45.80 10/EA	Add To Favorites
45-151823-50G	50 g	$35.90 1/EA	Add To Favorites
45-151823-100G	100 g	$61.60 1/EA	Add To Favorites
45-151823-250G	250 g	$146.00 1/EA	Add To Favorites
45-151823-1KG	1 kg	$515.00 1/EA	Add To Favorites

This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 151823-100G.

Properties
Descriptions
Safety Info.
Basic Data

assay	≥99% (CP)
bp	60.9 °C (lit.)
density	1.500 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/CHCl3/c2-1(3)4/h1H/i1D
InChI key	HEDRZPFGACZZDS-MICDWDOJSA-N
isotopic purity	99.8 atom % D
mass shift	M+1
mp	−64 °C (lit.)
Quality Level	200
refractive index	n20/D 1.444 (lit.)
SMILES string	[2H]C(Cl)(Cl)Cl
technique(s)	NMR: suitable

Application:	Chloroform-d has been employed as solvent in a ¹H NMR (Proton Nuclear Magnetic Resonance) spectroscopic study. It has been employed as solvent during the ³¹PNMR (Phosphorus-31 nuclear magnetic resonance) spectral investigation of triphenyl phosphate and tris(2-chloroethyl) phosphate. It has also been used as the deuterated solvent in the ¹H NMR spectral studies of 2-(4-bromobenzyl)-3-hydroxypropanoic acid and 3-hydroxy-2-(4-methoxybenzyl)propanoic acid. It has also been used as the deuterated solvent for the ¹HNMR spectral studies of 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxy-phenyl) hexafluoropropane dianhydride (6FDA) polyimide.
General description:	Chloroform-d (Deuterochloroform, CDCl₃), deuterated chloroform, is a standard purity solvent for NMR (Nuclear Magnetic Resonance) analyses. It is widely employed in high resolution NMR studies due to its high chemical and isotopic purity. Quantitaive infrared spectral investigations of carbon-deuterium stretching bands of chloroform-d in various organic solvents have been reported. Raman difference spectroscopic studies of mixtures of chloroform-d and liquid chloroform have been conducted to evaluate frequency shifts in the ν₁ and ν₂ bands of CHCl₃ and CDCl₃.
Packaging:	1 kg in glass bottle
Packaging:	10×0.6, 10×0.75, 10×1 mL in ampule
Packaging:	50, 100, 250 g in glass bottle

Symbol	GHS06,GHS08
Signal word	Danger
Hazard statements	H302 - H315 - H319 - H331 - H336 - H351 - H361d - H372
Precautionary statements	P202 - P301 + P312 - P302 + P352 - P304 + P340 + P311 - P305 + P351 + P338 - P308 + P313
Hazard Codes	Xn
Risk Statements	63-20/22-36/38-40-48/20
Safety Statements	36/37
RIDADR	UN 1888 6.1 / PGIII
WGK Germany	WGK 3

Purity	≥99% (CP)
bp	60.9 °C (lit.)
mp	−64 °C (lit.)
Density	1.500 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.444 (lit.)
UNSPSC	12142201

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