Diphenyl(p-tolyl)phosphine
ALDRICH/155039 - 96%
Synonym: (4-
CAS Number: 1031-93-2
Empirical Formula (Hill Notation): C19H17P
Molecular Weight: 276.31
EC Number: 213-848-3
MDL Number: MFCD00008543
Linear Formula: (C6H5)2PC6H4CH3
Product Type: Chemical
| assay | 96% |
| form | liquid |
| functional group | phosphine |
| InChI | 1S/C19H17P/c1-16-12-14-19 |
| InChI key | QJIMTLTYXBDJFC-UHFFFAOYSA |
| mp | 66-68 °C (lit.) |
| Quality Level | 100  |
| reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: ligand | |
| SMILES string | Cc1ccc(cc1)P(c2ccccc2)c3c |
| Application: | Reactant for: • Three-component cyclization • Probing coordination ability via a palladium pincer complex • Chelation-assisted hydroacylation of olefins with primary alcohols Reactant for synthesis of: • Trinuclear ruthenium carbonyl triarylphosphine cluster complexes • Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex • InP nanofibers / metal phosphide nanostructures • Peroxyl radical cations via pulse radiolysis one-electron oxidations |
| Packaging: | 10 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315 - H319 - H335 |
| Precautionary statements | P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 96% |
| mp | 66-68 °C (lit.) |
| UNSPSC | 12352002 |