1-Chloroisoquinoline
ALDRICH/156744 - 95%
CAS Number: 19493-44-8
Empirical Formula (Hill Notation): C9H6ClN
Molecular Weight: 163.60
MDL Number: MFCD00024134
Linear Formula: C9H6ClN
Product Type: Chemical
assay | 95% |
bp | 274-275 °C/768 mmHg (lit.) |
InChI | 1S/C9H6ClN/c10-9-8-4-2-1- |
InChI key | MSQCQINLJMEVNJ-UHFFFAOYSA |
mp | 31-36 °C (lit.) |
Quality Level | 100 |
SMILES string | Clc1nccc2ccccc12 |
Application: | The product has been used in a Mn-catalyzed cross-coupling with aryl- and alkylmagnesium halides. It has also been used in a Pd-catalyzed cross-coupling with heteroaryl boronic acids and esters. Furthermore, it has been used in a homocoupling reaction to yield bis-isoquinoline, each enantiomer of which might be very useful as a chiral ligand for asymmetric synthesis. |
Packaging: | 1, 5 g in glass bottle |
Symbol | GHS07 |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Purity | 95% |
bp | 274-275 °C/768 mmHg (lit.) |
mp | 31-36 °C (lit.) |
UNSPSC | 12352100 |