Methyl (triphenylphosphoranylidene)acetate
ALDRICH/157929 - 98%
Synonym: (Carbomethoxymethylene)
CAS Number: 2605-67-6
Empirical Formula (Hill Notation): C21H19O2P
Molecular Weight: 334.35
EC Number: 220-018-4
MDL Number: MFCD00008455
Linear Formula: (C6H5)3P=CHCO2CH3
Product Type: Chemical
assay | 98% |
form | powder |
InChI | 1S/C21H19O2P/c1-23-21(22) |
InChI key | NTNUDYROPUKXNA-UHFFFAOYSA |
mp | 168-172 °C (lit.) |
Quality Level | 200 |
reaction suitability | reaction type: C-C Bond Formation |
SMILES string | COC(=O)C=P(c1ccccc1)(c2cc |
Application: | Wittig reagent for the two-carbon homologation of aldehydes to α,β-unsaturated esters. Also used in an efficient synthesis of pyrazoles via reaction with methyl diazoacetate in the presence of triethylamine. |
Packaging: | 5, 25, 100 g in poly bottle |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 98% |
mp | 168-172 °C (lit.) |
UNSPSC | 12352108 |