Thallium(III) nitrate trihydrate

ALDRICH/163015

Synonym: TTN; Thallium trinitrate

CAS Number: 13453-38-8
Empirical Formula (Hill Notation): N₃O₉Tl · 3H₂O
Molecular Weight: 444.44
EC Number: 237-325-4
MDL Number: MFCD00149874
Linear Formula: Tl(NO₃)₃ · 3H₂O
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-163015-25G	25 g	$328.00 1/EA		Add To Favorites
45-163015-100G	100 g	$1090.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

InChI	1S/3NO3.3H2O.Tl/c32-1(3)4;;;;/h;;;31H2;/q3*-1;;;;+3
InChI key	ZCPIKMRXMBJLCP-UHFFFAOYSA-N
mp	102-105 °C (lit.)
Quality Level	100
reaction suitability	core: thallium
	reagent type: catalyst
SMILES string	O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

Application:	Reagent for the rapid oxidation of styrene derivatives to carbonyl compounds, for the regioselective ring expansion of cyclic aralkyl ketones via oxidative rearrangement, for the selective hydrolysis of thioacetals to carbonyl compounds and for a general synthetic method to 19-norsteroids. Mediates ring contraction of cyclic ketones to a series of trans-fused 10-methyl-2-decalones.
Packaging:	25, 100 g in glass bottle

Symbol	GHS03,GHS06,GHS08,GHS09
Signal word	Danger
Hazard statements	H272 - H300 + H330 - H373 - H411
Precautionary statements	P210 - P220 - P260 - P273 - P304 + P340 + P310 - P314
Hazard Codes	T+,N
Risk Statements	26/28-33-51/53
Safety Statements	13-28-45-61
RIDADR	UN 2727 5.1(6.1) / PGII
WGK Germany	WGK 2
Flash Point(F)	Not applicable
Flash Point(C)	Not applicable

mp	102-105 °C (lit.)
UNSPSC	12352300

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