Ethyl malonyl chloride
ALDRICH/163872 - technical grade
Synonym: Ethyl (chloroformyl)
CAS Number: 36239-09-5
Empirical Formula (Hill Notation): C5H7ClO3
Molecular Weight: 150.56
EC Number: 252-934-5
MDL Number: MFCD00000736
Linear Formula: CH3CH2OCOCH2COCl
Product Type: Chemical
| bp | 79-80 °C/25 mmHg (lit.) |
| density | 1.176 g/mL at 25 °C (lit.) |
| functional group | acyl chloride |
| ester | |
| grade | technical grade |
| InChI | 1S/C5H7ClO3/c1-2-9-5(8)3- |
| InChI key | KWFADUNOPOSMIJ-UHFFFAOYSA |
| Quality Level | 200  |
| refractive index | n |
| SMILES string | CCOC(=O)CC(Cl)=O |
| storage temp. | 2-8°C |
| Application: | Ethyl malonyl chloride was used in the synthesis of: • liquid-crystalline methanofullerodendrimers • 3,5-disubstituted 1,2,4-oxadiazole derivatives, which are potential peptidomimetic building blocks • 3-pyrrolin-2-ones via amidation with propargylamines and subsequent base catalyzed 5-exo-dig cyclization |
| Application: | Versatile acylating agent for propargyl alcohols, hydrazines, and amines. |
| General description: | Ethyl malonyl chloride is a versatile acylating agent for propargyl alcohols, hydrazines and amines. |
| Packaging: | 5, 25 g in glass bottle |
| Symbol |  GHS05 |
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P280 - P305 + P351 + P338 - P310 |
| Hazard Codes | C |
| Risk Statements | 14-34 |
| Safety Statements | 7-26-36/37/39-45 |
| RIDADR | UN 3265 8 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | 147.2 °F - closed cup |
| Flash Point(C) | 64 °C - closed cup |
| Supplemental Hazard Statements | EUH014 |
| bp | 79-80 °C/25 mmHg (lit.) |
| Density | 1.176 g/mL at 25 °C (lit.) |
| Refractive Index | n |
| Storage Temp. | 2-8°C |
| UNSPSC | 12352100 |