Dibenzyl azodicarboxylate
ALDRICH/166804 - technical grade, 90%
CAS Number: 2449-05-0
Empirical Formula (Hill Notation): C16H14N2O4
Molecular Weight: 298.29
EC Number: 219-508-0
MDL Number: MFCD00016737
Linear Formula: C6H5CH2OCON=NCOOCH2C6H5
Product Type: Chemical
assay | 90% |
form | solid |
grade | technical grade |
InChI | 1S/C16H14N2O4/c19-15(21-1 |
InChI key | IRJKSAIGIYODAN-ISLYRVAYSA |
mp | 43-47 °C (lit.) |
Quality Level | 100 ![]() |
SMILES string | O=C(OCc1ccccc1)N=NC(=O) |
storage temp. | 2-8°C |
Application: | Dibenzyl azodicarboxylate was used as electrophilic reagent in the synthesis of C-glycosyl α-amino acids via proline-catalyzed α-amination of C-glycosylalkyl aldehydes. It was used in enantioselective synthesis of optically active pyrazolidine derivatives. |
General description: | Dibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides. |
Packaging: | 5, 25 g in glass bottle |
Symbol | ![]() |
Signal word | Warning |
Hazard statements | H315 - H319 - H335 |
Precautionary statements | P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26 |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Purity | 90% |
mp | 43-47 °C (lit.) |
Storage Temp. | 2-8°C |
UNSPSC | 12352100 |