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Dibenzyl azodicarboxylate

ALDRICH/166804 - technical grade, 90%

CAS Number: 2449-05-0
Empirical Formula (Hill Notation): C16H14N2O4
Molecular Weight: 298.29
EC Number: 219-508-0
MDL Number: MFCD00016737
Linear Formula: C6H5CH2OCON=NCOOCH2C6H5
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-166804-5G 5 g
 $0.00
1/EA
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45-166804-25G 25 g
 $555.00
1/EA		 Add To Favorites

 

assay 90%
form solid
functional group azo
  phenyl
grade technical grade
InChI 1S/C16H14N2O4/c19-15(21-11-13-7-3-1-4-8-13)17-18-16(20)22-12-14-9-5-2-6-10-14/h1-10H,11-12H2/b18-17+
InChI key IRJKSAIGIYODAN-ISLYRVAYSA-N
mp 43-47 °C (lit.)
Quality Level 100 
SMILES string O=C(OCc1ccccc1)N=NC(=O)OCc2ccccc2
storage temp. 2-8°C
Application: Dibenzyl azodicarboxylate was used as electrophilic reagent in the synthesis of C-glycosyl α-amino acids via proline-catalyzed α-amination of C-glycosylalkyl aldehydes. It was used in enantioselective synthesis of optically active pyrazolidine derivatives.
General description: Dibenzyl azodicarboxylate undergoes[4+2] cycloaddition reaction with glycal to yield 2-aminoglycosides.
Packaging: 5, 25 g in glass bottle
Purity 90%
mp 43-47 °C (lit.)
Storage Temp. 2-8°C
UNSPSC 12352100

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