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Ethyl 2-oxocyclopentanecarboxylate

ALDRICH/168092 - 95%

Synonym: 2-(Ethoxycarbonyl)cyclopentanone; Ethyl cyclopentanone-2-carboxylate

CAS Number: 611-10-9
Empirical Formula (Hill Notation): C8H12O3
Molecular Weight: 156.18
EC Number: 210-253-0
MDL Number: MFCD00001412
Linear Formula: (O=)C5H7CO2C2H5
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-168092-25G 25 g
 $53.30
1/EA		 Add To Favorites
45-168092-100G 100 g
 $147.00
1/EA		 Add To Favorites

 

assay 95%
bp 102-104 °C/11 mmHg (lit.)
density 1.054 g/mL at 25 °C (lit.)
InChI 1S/C8H12O3/c1-2-11-8(10)6-4-3-5-7(6)9/h6H,2-5H2,1H3
InChI key JHZPNBKZPAWCJD-UHFFFAOYSA-N
Quality Level 200 
refractive index n20/D 1.452 (lit.)
SMILES string CCOC(=O)C1CCCC1=O
Application: Ethyl 2-oxocyclopentanecarboxylate was used in stereoselective synthesis of (±)-cis,cis-spiro[4.4]nonane-1,6-diol. It was also used in the synthesis of tanikolide.
General description: Phase-transfer benzylation reaction of ethyl 2-oxocyclopentanecarboxylate with benzyl bromide in microreactor has been investigated. Ethyl 2-oxocyclopentanecarboxylate participates in cobalt (II) Schiff′s base complex catalyzed oxidation of primary and secondary alcohols.
Packaging: 25, 100 g in glass bottle
RIDADR NONH for all modes of transport
WGK Germany WGK 3
Flash Point(F) 170.6 °F - closed cup
Flash Point(C) 77 °C - closed cup
Purity 95%
bp 102-104 °C/11 mmHg (lit.)
Density 1.054 g/mL at 25 °C (lit.)
Refractive Index n20/D 1.452 (lit.)
UNSPSC 12352100

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