Phenylmagnesium bromide solution

ALDRICH/171565 - 3.0 M in diethyl ether

Synonym: Bromomagnesiobenzene; Bromophenylmagnesium

CAS Number: 100-58-3
Empirical Formula (Hill Notation): C₆H₅BrMg
Molecular Weight: 181.31
MDL Number: MFCD00000038
Linear Formula: C₆H₅MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-171565-4X25ML	25 mL	No Price
45-171565-50ML	50 mL	$72.40 1/EA		Add To Favorites
45-171565-100ML	100 mL	$98.90 1/EA		Add To Favorites
45-171565-800ML	800 mL	$469.00 1/EA		Add To Favorites
45-171565-18L	18 L	$3280.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	3.0 M in diethyl ether
density	1.134 g/mL at 25 °C
InChI	1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key	ANRQGKOBLBYXFM-UHFFFAOYSA-M
Quality Level	200
reaction suitability	reaction type: Grignard Reaction
SMILES string	Br[Mg]c1ccccc1

Application:	Phenylmagnesium bromide was used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It was also used for the monoalkylation of aliphatic primary amine to generate secondary amines by the Grignard reaction of 1-[(alkylamino) methyl] benzotriazoles. It may be used for synthesis of the following: • 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol • 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol • (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent • series of o-substituted benzophenones
General description:	Phenylmagnesium bromide solution contains 3M phenylmagnesium bromide in diethyl ether. It can act as a strong acid and Lewis acid. It can undergo addition reaction with many unsaturated functional groups. The phenyl group can displace halide from other organic compounds. Phenylmagnesium bromide is a Grignard reagent. Reaction of β-cyclohexanedione (dihydroresorcinol) with phenylmagnesium bromide has been investigated.
Other Notes:	Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid
Packaging:	18 L in Kilo-Lab™
Packaging:	50, 100, 800 mL in Sure/Seal™
Packaging:	View returnable container options .

Symbol	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H225 - H314 - H336
Precautionary statements	P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14-19-22-34-67
Safety Statements	9-16-26-33-36/37/39-45
RIDADR	UN 2924 8(3) / PGII
WGK Germany	WGK 3
Flash Point(F)	-40.0 °F - closed cup
Flash Point(C)	-40 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	1.134 g/mL at 25 °C
UNSPSC	12352103

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