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Lithium tetrakis(pentafluorophenyl)borate ethyl etherate

ALDRICH/17324

Synonym: Tetrakis(pentafluorophenyl)boron lithium ethyl etherate

CAS Number: 371162-53-7
Empirical Formula (Hill Notation): C24BF20Li · 2.5C4H10O
Molecular Weight: 871.28
MDL Number: MFCD01861289
Linear Formula: C24BF20Li · 2.5C4H10O
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-17324-100MG 100 mg
 $85.30
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InChI 1S/C24BF20.C4H10O.Li/c26-5-1(6(27)14(35)21(42)13(5)34)25(2-7(28)15(36)22(43)16(37)8(2)29,3-9(30)17(38)23(44)18(39)10(3)31)4-11(32)19(40)24(45)20(41)12(4)33;1-3-5-4-2;/h;3-4H2,1-2H3;/q-1;;+1
InChI key KPLZKJQZPFREPG-UHFFFAOYSA-N
mp 117-122 °C
Quality Level 100 
reaction suitability core: boron
  reagent type: catalyst
SMILES string [Li+].CCOCC.Fc1c(F)c(F)c(c(F)c1F)[B-](c2c(F)c(F)c(F)c(F)c2F)(c3c(F)c(F)c(F)c(F)c3F)c4c(F)c(F)c(F)c(F)c4F
Application: Lithium tetrakis(pentafluorophenyl)borate ethyl etherate can be used as:
•  A coordinating counter anion in electrochemical reactions along with transition metal catalysts to enhance their acidity or solubility.
• A catalyst in the Baeyer-Villiger oxidation of cycloalkanones to obtain lactones in the presence of aqueous hydrogen peroxide and oxalic acid.
• An activator in the synthesis of poly(norbornene ester)s.
Other Notes: Salt for the generation of cationic transition metal complexes
Packaging: 100 mg in glass bottle
Packaging: Bottomless glass bottle. Contents are inside inserted fused cone.
mp 117-122 °C
UNSPSC 12352300

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