Borane tetrahydrofuran complex solution

ALDRICH/176192 - 1.0 M in THF

CAS Number: 14044-65-6
Empirical Formula (Hill Notation): C₄H₁₁BO
Molecular Weight: 85.94
MDL Number: MFCD00012429
Linear Formula: BH₃OC₄H₈
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-176192-4X25ML	25 mL	$60.80 4/EA		Add To Favorites
45-176192-100ML	100 mL	$63.90 1/EA		Add To Favorites
45-176192-800ML	800 mL	$291.00 1/EA		Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in THF
contains	<0.005 M sodium borohydride as stabilizer
density	0.898 g/mL at 25 °C
InChI	1S/C4H8O.BH3/c1-2-4-5-3-1;/h1-4H2;1H3
InChI key	RMCYTHFAWCWRFA-UHFFFAOYSA-N
Quality Level	200
reaction suitability	reagent type: reductant
SMILES string	B.C1CCOC1
storage temp.	2-8°C

Application:	New, Safer, NIMBA-Stabilized BH3 THF Solutions
Application:	BH₃-THF can be used as a reducing agent for the reduction of various functional groups such as carboxylic acids, aldehydes, ketones, esters, acid chlorides, nitriles, epoxides, amides, lactones, oximes, and imines into corresponding alcohols and amines. Grignard reagents, arylmercury, arylthalium, and allyl and propargyllithium compounds react with BH₃−THF to give organoboranes, which can be oxidized to the corresponding alcohols, phenols, and 1,3-diols. It can also be used: • To synthesize the chiral borane catalyst, which is used in the enantioselective halo-aldol reaction. • To prepare 9-unsubstituted acridines by reduction of corresponding acridones. • To reduce nylon surface amide groups to secondary amines.
General description:	Borane tetrahydrofuran complex (BH₃-THF) is widely used as a reducing agent in organic synthesis. It is also used as a reagent in hydroboration reactions.
Legal Information:	Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging:	4×25, 100, 800 mL in Sure/Seal™
Packaging:	The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H260 - H302 - H318 - H335 - H351
Precautionary statements	P201 - P210 - P231 + P232 - P280 - P305 + P351 + P338 + P310 - P308 + P313
Hazard Codes	F,Xi
Risk Statements	11-14/15-19-22-37/38-41
Safety Statements	16-26-33-43
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH018 - EUH019

Density	0.898 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352005

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