DPPF
ALDRICH/177261 - 97%
Synonym: 1,1′-Ferrocenediyl-bis(diphenylphosphine); dppf
CAS Number: 12150-46-8
Empirical Formula (Hill Notation): C34H28FeP2
Molecular Weight: 554.38
MDL Number: MFCD00001422
Linear Formula: C34H28FeP2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 177261-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 177261-10G
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.
| assay | 97% |
| form | powder |
| functional group | phosphine |
| greener alternative category | Aligned  , |
| greener alternative product characteristics | Catalysis Learn more about the Principles of Green Chemistry . |
| InChI | 1S/2C17H14P.Fe/c2*1-3-9-1 |
| InChI key | HPXNTHKXCYMIJL-UHFFFAOYSA |
| mp | 181-182 °C (dec.) (lit.) |
| Quality Level | 200 |
| reaction suitability | reaction type: Cross Couplings |
| reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction |
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| reagent type: ligand reaction type: Carbonylations |
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| reagent type: ligand reaction type: Ene Reaction |
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| reagent type: ligand reaction type: Heck Reaction |
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| reagent type: ligand reaction type: Negishi Coupling |
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| reagent type: ligand reaction type: Sonogashira Coupling |
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| reagent type: ligand reaction type: Stille Coupling |
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| reagent type: ligand reaction type: Suzuki-Miyaura Coupling |
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| reagent type: ligand reaction type: Tsuji-Trost Reaction |
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| SMILES string | [Fe].[CH]1[CH][CH][C]([CH |
| sustainability | Greener Alternative Product |
| Application: | Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology  |
| Application: | Ligand used in a Pd(II)-catalyzed cross-coupling synthesis of oxazepine ring systems. |
| General description: | Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation. |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information. |
| Packaging: | 1, 10, 25, 250 g in glass bottle |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 181-182 °C (dec.) (lit.) |
| UNSPSC | 12350000 |