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L-Selectride® solution

ALDRICH/178497 - 1.0 M in THF

Synonym: Lithium tri-sec-butylborohydride solution

CAS Number: 38721-52-7
Empirical Formula (Hill Notation): C12H28BLi
Molecular Weight: 190.10
MDL Number: MFCD00011708
Linear Formula: Li[CH(CH3)CH2CH3]3BH
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-178497-100ML 100 mL
 $89.30
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45-178497-800ML 800 mL
 $465.00
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45-178497-8L 8 L
 $2150.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

concentration 1.0 M in THF
density 0.89 g/mL at 25 °C
form liquid
InChI 1S/C12H28B.Li/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h10-13H,7-9H2,1-6H3;/q-1;+1
InChI key ACJKNTZKEFMEAK-UHFFFAOYSA-N
Quality Level 200 
reaction suitability reagent type: reductant
SMILES string [Li+].[H][B-](C(C)CC)(C(C)CC)C(C)CC
Application: • Reducing agent

Reagent for:
• Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters
• Diastereoselective reduction reactions
• Hydride reduction of the Danishefsky pyranones
• Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes
• Synthesis of alkanols by carbonylation reactions
Application: L-Selectride® can be used as a reagent for:
•  The stereoselective reduction of ketone to alcohol.
•  The selective demethylation of tert alcohol.
Application: L-Selectride® solution may be used in the O-demethylation and N-demethylation of opium alkaloids and their derivatives.
General description: L-Selectride® is an air and water sensitive solution mainly used as a bulky stereoselective hydride reducing agent.
Legal Information: Selectride is a registered trademark of Merck KGaA, Darmstadt, Germany
Packaging: 100, 800 mL in Sure/Seal™
Packaging: 8, 18 L in Kilo-Lab™
Packaging: View returnable container options .
Density 0.89 g/mL at 25 °C
UNSPSC 12352000

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