Diphenyl phosphoryl azide
ALDRICH/178756 - 97%
Synonym: DPPA; Phosphoric acid diphenyl ester azide
CAS Number: 26386-88-9
Empirical Formula (Hill Notation): C12H10N3O3P
Molecular Weight: 275.20
EC Number: 247-644-0
MDL Number: MFCD00001987
Linear Formula: (C6H5O)2P(O)N3
Product Type: Chemical
assay | 97% |
bp | 157 °C/0.17 mmHg (lit.) |
density | 1.277 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C12H10N3O3P/c13-14-15- |
InChI key | SORGEQQSQGNZFI-UHFFFAOYSA |
Quality Level | 200 |
reaction suitability | reaction type: click chemistry |
refractive index | n |
SMILES string | [N-]=[N+]=NP(=O)(Oc1ccccc |
storage temp. | 2-8°C |
Application: | Hydroazidation Catalyst for Facile Preparation of Organoazides Reagent for synthesis of oligosaccharides linked with carbamate and urea bonds utilizing modified Curtis rearrangement |
Application: | Aziridination of olefins catalyzed by colbalt-tetraphenylporphy |
Application: | Used as the activating agent in the preparation of macrocyclic lactams and of an aldose reductase inhibitor. |
Packaging: | 5 kg in poly drum |
Packaging: | 5, 25, 100, 500 g in glass bottle |
Symbol | GHS06 |
Signal word | Danger |
Hazard statements | H301 + H311 + H331 - H315 - H319 - H335 |
Precautionary statements | P261 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311 - P305 + P351 + P338 |
Hazard Codes | T |
Risk Statements | 23/24/25-36/37/38 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3278 6.1 / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | 233.6 °F - closed cup |
Flash Point(C) | 112 °C - closed cup |
Purity | 97% |
bp | 157 °C/0.17 mmHg (lit.) |
Density | 1.277 g/mL at 25 °C (lit.) |
Refractive Index | n |
Storage Temp. | 2-8°C |
UNSPSC | 12352302 |