Boron trichloride solution
ALDRICH/178934 - 1.0 M in methylene chloride
Synonym: Boron chloride; Trichloroborane; Trichloroborane
CAS Number: 10294-34-5
Empirical Formula (Hill Notation): BCl3
Molecular Weight: 117.17
MDL Number: MFCD00011313
Linear Formula: BCl3
Product Type: Chemical
concentration | 1.0 M in methylene chloride |
density | 1.326 g/mL at 25 °C |
form | liquid |
InChI | 1S/BCl3/c2-1(3)4 |
InChI key | FAQYAMRNWDIXMY-UHFFFAOYSA |
Quality Level | 200 |
reaction suitability | core: boron |
reagent type: catalyst | |
reagent type: Lewis acid | |
SMILES string | ClB(Cl)Cl |
storage temp. | 2-8°C |
vapor pressure | 29.72 psi ( 55 °C) |
9.05 psi ( 20 °C) |
Application: | Boron trichloride may be used in the synthesis of Cl-BODIPYs (BODIPY - Boron-dipyrromethene) and tris(dimethylamino)borane |
Application: | For preparing methyl esters of fatty acids and for transesterification of triglycerides. |
General description: | Boron trichloride is a boron halide. It participates in the hydroboration of alkenes. It forms strongly polarized donor-acceptor complexes with trimethyl- and triethylsilyl triflate. Boron trichloride assisted reaction between acid chlorides and alkynyltrifluoroborate salts have been reported to form ynones. Boron trichloride solution is used as a Lewis acid catalyst in the synthesis of BN-phenanthrenes. |
Legal Information: | Sure/Seal is a trademark of Sigma-Aldrich Co. LLC |
Packaging: | 2 L in Sure/Seal™ |
Packaging: | 4×25, 100, 800 mL in Sure/Seal™ |
Packaging: | The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product. |
Symbol | GHS05,GHS06,GHS08 |
Signal word | Danger |
Hazard statements | H301 + H331 - H314 - H336 - H351 - H360FD |
Precautionary statements | P202 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
Hazard Codes | T+ |
Risk Statements | 14-26/28-36/37/38-40 |
Safety Statements | 26-28-36/37-45 |
RIDADR | UN 2922 6.1(8) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Density | 1.326 g/mL at 25 °C |
Storage Temp. | 2-8°C |
UNSPSC | 12352106 |