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Boron trichloride solution

ALDRICH/178934 - 1.0 M in methylene chloride

Synonym: Boron chloride; Trichloroborane; Trichloroborane

CAS Number: 10294-34-5
Empirical Formula (Hill Notation): BCl3
Molecular Weight: 117.17
MDL Number: MFCD00011313
Linear Formula: BCl3
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-178934-4X25ML 25 mL
$105.00
4/EA
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45-178934-100ML 100 mL
$110.00
1/EA
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45-178934-800ML 800 mL
$491.00
1/EA
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45-178934-2L 2 L
$802.00
1/EA
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25 mL Sure/Sealâ„¢ Packaging

 

concentration 1.0 M in methylene chloride
density 1.326 g/mL at 25 °C
form liquid
InChI 1S/BCl3/c2-1(3)4
InChI key FAQYAMRNWDIXMY-UHFFFAOYSA-N
Quality Level 200 
reaction suitability core: boron
  reagent type: catalyst
  reagent type: Lewis acid
SMILES string ClB(Cl)Cl
storage temp. 2-8°C
vapor pressure 29.72 psi ( 55 °C)
  9.05 psi ( 20 °C)
Application: Boron trichloride may be used in the synthesis of Cl-BODIPYs (BODIPY - Boron-dipyrromethene) and tris(dimethylamino)borane. It may be used in the synthesis of sceptrins and nakamuric acid.
Application: For preparing methyl esters of fatty acids and for transesterification of triglycerides.
General description: Boron trichloride is a boron halide. It participates in the hydroboration of alkenes. It forms strongly polarized donor-acceptor complexes with trimethyl- and triethylsilyl triflate. Boron trichloride assisted reaction between acid chlorides and alkynyltrifluoroborate salts have been reported to form ynones.

Boron trichloride solution is used as a Lewis acid catalyst in the synthesis of BN-phenanthrenes.
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 2 L in Sure/Seal™
Packaging: 4×25, 100, 800 mL in Sure/Seal™
Packaging: The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Density 1.326 g/mL at 25 °C
Storage Temp. 2-8°C
UNSPSC 12352106

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