Borane pyridine complex
ALDRICH/179752 - ~8 M BH3
Synonym: NSC 10219; NSC 53324; Pyridine borane; Trihydro(pyridine)
CAS Number: 110-51-0
Empirical Formula (Hill Notation): C5H8BN
Molecular Weight: 92.93
MDL Number: MFCD00012435
Linear Formula: C5H8BN
Product Type: Chemical
concentration | ~8 M BH3 |
density | 0.92 g/mL at 25 °C (lit.) |
form | liquid |
InChI | 1S/C5H8BN/c6-7-4-2-1-3-5- |
InChI key | LPGWNCNRGQANGC-UHFFFAOYSA |
mp | 10-11 °C (lit.) |
Quality Level | 200 |
reaction suitability | reagent type: reductant |
refractive index | n |
SMILES string | [BH3-][n+]1ccccc1 |
storage temp. | 2-8°C |
Application: | Borane pyridine complex is commonly used as a reducing reagent for the reductive amination of aldehydes and ketones. It is the precursor to synthesize carbon-based material, BC4N. Along with iodine, it can be used as a reagent for hydroboration of alkenes and alkynes. |
Application: | Used for: • Investigations of site energy distribution functions from Toth isotherm for adsorption of gases on heterogeneous surfaces • Preparation of α−alkyl-β-hydroxy esters • Regioselective immobilization of short oligonucleotides to acrylic copolymer gels • Preparation of Igs conjugated with viral peptide epitopes • Sintering of silicon carbide Reducing agent for high performance liquid chromatography analysis of oligosaccharides Modifier in decant oil affecting its carbonization to mesophase pitch |
Caution: | May darken in storage. |
Other Notes: | may contain excess pyridine |
Packaging: | 5, 25, 100 g in Sure/Seal™ |
Symbol | GHS02,GHS06 |
Signal word | Danger |
Hazard statements | H225 - H301 + H311 - H315 - H319 - H330 |
Precautionary statements | P210 - P233 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 |
Hazard Codes | T+ |
Risk Statements | 10-24/25-26-36/38 |
Safety Statements | 26-28-36/37-45 |
RIDADR | UN 1992 6.1(3) / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | 69.8 °F |
Flash Point(C) | 21 °C |
mp | 10-11 °C (lit.) |
Density | 0.92 g/mL at 25 °C (lit.) |
Refractive Index | n |
Storage Temp. | 2-8°C |
UNSPSC | 12352005 |