Borane tert-butylamine complex
ALDRICH/180211 - powder, 97%
Synonym: tert-Butylamine borane; NSC 114045; Trihydro(2-
CAS Number: 7337-45-3
Empirical Formula (Hill Notation): C4H14BN
Molecular Weight: 86.97
EC Number: 230-851-5
MDL Number: MFCD00075635
Linear Formula: (CH3)3CNH2 · BH3
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 180211-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 180211-25G
| assay | 97% |
| form | powder |
| InChI | 1S/C4H11N.BH3/c1-4(2,3)5; |
| InChI key | GKFJEDWZQZKYHV-UHFFFAOYSA |
| mp | 98-100 °C (dec.) (lit.) |
| Quality Level | 100  |
| reaction suitability | reagent type: reductant |
| SMILES string | B.CC(C)(C)N |
| Application: | Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses: • copper (I) oxide nanoparticles • diphosphine-protected gold nanocluster • 4-acetoxycinnamyl alcohols |
| Application: | Reactant involved in: • Non-destructive analyses and conservation treatments of Indian drawings • Dehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexes • The formation of σ-borane complexes • Ethanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefins • Photochemical hydroboration and oxidation of single-walled carbon nanotubes |
| General description: | Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts. |
| Packaging: | 25, 100 g in glass bottle |
| Symbol |   GHS06,GHS09 |
| Signal word | Danger |
| Hazard statements | H301 + H311 - H315 - H319 - H411 |
| Precautionary statements | P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338 |
| Hazard Codes | T |
| Risk Statements | 21-25-36/37/38 |
| Safety Statements | 26-36/37-45 |
| RIDADR | UN 2811 6.1 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 97% |
| mp | 98-100 °C (dec.) (lit.) |
| UNSPSC | 12352116 |