2′-Bromoacetophenone

ALDRICH/183695 - 99%

Synonym: 1-Acetyl-2-bromobenzene

CAS Number: 2142-69-0
Empirical Formula (Hill Notation): C₈H₇BrO
Molecular Weight: 199.04
EC Number: 218-398-1
MDL Number: MFCD00000067
Linear Formula: BrC₆H₄COCH₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-183695-5G	5 g	$60.40 1/EA		Add To Favorites
45-183695-25G	25 g	$134.00 1/EA		Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

assay	99%
density	1.476 g/mL at 25 °C (lit.)
form	liquid
InChI	1S/C8H7BrO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
InChI key	PIMNFNXBTGPCIL-UHFFFAOYSA-N
Quality Level	100
refractive index	n20/D 1.568 (lit.)
SMILES string	CC(=O)c1ccccc1Br

Application:	2′-Bromoacetophenone (2-Bromoacetophenone) was used in the synthesis of novel series of non-condensed 5,5-bicycles.
General description:	2′-Bromoacetophenone (2-Bromoacetophenone) undergoes enantioselective addition reaction with phenylacetylene catalyzed by chiral camphorsulfonamide. It reacts with aliphatic primary amines in the presence of palladium catalyst to afford 3-methyleneisoindolin-1-ones.
Packaging:	5, 25 g in glass bottle

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	NONH for all modes of transport
WGK Germany	WGK 3
Flash Point(F)	230.0 °F - closed cup
Flash Point(C)	110 °C - closed cup

Purity	99%
Density	1.476 g/mL at 25 °C (lit.)
Refractive Index	n20/D 1.568 (lit.)
UNSPSC	12352100

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