Ethylmagnesium bromide solution

ALDRICH/189871 - 3.0 M in diethyl ether

Synonym: EtMgBr solution

CAS Number: 925-90-6
Empirical Formula (Hill Notation): C₂H₅BrMg
Molecular Weight: 133.27
MDL Number: MFCD00000043
Linear Formula: CH₃CH₂MgBr
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-189871-4X25ML	25 mL	$64.50 4/EA		Add To Favorites
45-189871-100ML	100 mL	$68.00 1/EA		Add To Favorites
45-189871-800ML	800 mL	$349.00 1/EA		Add To Favorites
45-189871-8L	8 L	$2480.00 1/EA		Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

bp	34.6 °C/1.013 hPa
concentration	3.0 M in diethyl ether
density	1.02 g/mL at 25 °C
form	liquid
InChI	1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1
	[1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1]
InChI key	TWTWFMUQSOFTRN-UHFFFAOYSA-M
	[HSNUIYJWTSJUMS-UHFFFAOYSA-N]
Quality Level	100
reaction suitability	reaction type: Grignard Reaction
SMILES string	CC[Mg]Br
	[CC[Mg]Br]

Application:	Ethylmagnesium bromide solution (3.0 M in diethyl ether) can be used for copper(I)-catalyzed allylic substitution reaction.
General description:	Ethylmagnesium bromide, an organomagnesium compound, is commonly known as Grignard reagent. It is a powerful carbon nucleophile mainly used for C-C bond formation.
Legal Information:	Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging:	4×25, 100, 800 mL in Sure/Seal™
Packaging:	8 L in Kilo-Lab™
Packaging:	The 25 mL Sure/Seal^™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Packaging:	View returnable container options .

Symbol	GHS02,GHS05,GHS07
Signal word	Danger
Hazard statements	H225 - H260 - H302 - H314 - H336
Precautionary statements	P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
Hazard Codes	F,C
Risk Statements	11-14/15-19-22-34-67
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 1
Flash Point(F)	-40.0 °F - closed cup
Flash Point(C)	-40 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

bp	34.6 °C/1.013 hPa
Density	1.02 g/mL at 25 °C
UNSPSC	12352103

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