Ethylmagnesium bromide solution
ALDRICH/189871 - 3.0 M in diethyl ether
Synonym: EtMgBr solution
CAS Number: 925-90-6
Empirical Formula (Hill Notation): C2H5BrMg
Molecular Weight: 133.27
MDL Number: MFCD00000043
Linear Formula: CH3CH2MgBr
Product Type: Chemical
concentration | 3.0 M in diethyl ether |
density | 1.02 g/mL at 25 °C |
InChI | 1S/C2H5.BrH.Mg/c1-2;;/h1H |
InChI key | TWTWFMUQSOFTRN-UHFFFAOYSA |
Quality Level | 100 |
reaction suitability | reaction type: Grignard Reaction |
SMILES string | CC[Mg]Br |
Application: | Ethylmagnesium bromide solution (3.0 M in diethyl ether) can be used for copper(I)-catalyzed allylic substitution reaction. |
General description: | Ethylmagnesium bromide, an organomagnesium compound, is commonly known as Grignard reagent. It is a powerful carbon nucleophile mainly used for C-C bond formation. |
Legal Information: | Sure/Seal is a trademark of Sigma-Aldrich Co. LLC |
Packaging: | 4×25, 100, 800 mL in Sure/Seal™ |
Packaging: | 8 L in Kilo-Lab™ |
Packaging: | The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product. |
Packaging: | View returnable container options . |
Symbol | GHS02,GHS05,GHS07 |
Signal word | Danger |
Hazard statements | H225 - H260 - H302 - H314 - H336 |
Precautionary statements | P210 - P231 + P232 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | F,C |
Risk Statements | 11-14/15-19-22-34-67 |
Safety Statements | 16-26-36/37/39-43-45 |
RIDADR | UN 3399A 4.3(3) / PGI |
WGK Germany | WGK 1 |
Flash Point(F) | -40.0 °F - closed cup |
Flash Point(C) | -40 °C - closed cup |
Supplemental Hazard Statements | EUH014 - EUH019 |
Density | 1.02 g/mL at 25 °C |
UNSPSC | 12352103 |