Borane dimethyl sulfide complex solution

ALDRICH/192120 - 2.0 M in THF

Synonym: BMS; Trihydro[thiobis[methane]]boron

CAS Number: 13292-87-0
Empirical Formula (Hill Notation): C₂H₉BS
Molecular Weight: 75.97
MDL Number: MFCD00013189
Linear Formula: (CH₃)₂S · BH₃
Product Type: Chemical

Catalog Number	PKG Qty.	Price	Quantity


45-192120-4X25ML	25 mL	$80.30 1/EA		Add To Favorites
45-192120-100ML	100 mL	$82.60 1/EA		Add To Favorites
45-192120-800ML	800 mL	$625.00 1/EA		Add To Favorites

25 mL Sure/Seal™ Packaging

Properties
Descriptions
Safety Info.
Basic Data

concentration	2.0 M in THF
density	0.855 g/mL at 25 °C
form	liquid
InChI	1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
InChI key	RMHDLBZYPISZOI-UHFFFAOYSA-N
Quality Level	200
reaction suitability	reagent type: reductant
SMILES string	B.CSC
storage temp.	2-8°C

Application:	Borane dimethyl sulfide complex (BMS) solution may be used in the following studies: • One-pot conversion of alkynes into 1,2-diols. • Preparation of iminopentitols. • Reduction of representative organic functional groups, such as esters, nitriles and amides. • Used along with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. • Asymmetric reduction of ferrocenyl-1,3-diketones to chiral 1,3-diols. • Highly enantioselective reduction of ketones catalyzed by C₃-symmetric tripodal hydroxyamides.
Application:	Reactant used as a regioselective reducing agent Reactant involved in: • Hydroboration / oxidation Synthesis of cage compounds
General description:	Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported.
Packaging:	100, 800 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H260 - H302 + H312 - H318 - H335 - H336 - H351 - H360FD
Precautionary statements	P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 - P308 + P313
Hazard Codes	F,Xn
Risk Statements	11-14/15-19-37-40-41
Safety Statements	16-26-36/37/39-43
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 1
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	0.855 g/mL at 25 °C
Storage Temp.	2-8°C
UNSPSC	12352112

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