Advanced Search



Trimethylaluminum solution

ALDRICH/198048 - 2.0 M in toluene

Synonym: Trimethylalane

CAS Number: 75-24-1
Empirical Formula (Hill Notation): C3H9Al
Molecular Weight: 72.09
MDL Number: MFCD00008252
Linear Formula: (CH3)3Al
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-198048-4X25ML 25 mL
 $93.00
4/EA		 Add To Favorites
45-198048-100ML 100 mL
 $97.90
1/EA		 Add To Favorites
45-198048-800ML 800 mL
 $494.00
1/EA		 Add To Favorites
45-198048-1L 1 L
 $550.00
1/EA		 Add To Favorites
45-198048-8L 8 L
 $2120.00
1/EA		 Add To Favorites
25 mL Sure/Seal™ Packaging

 

concentration 2.0 M in toluene
density 0.81 g/mL at 25 °C
form liquid
InChI 1S/3CH3.Al/h3*1H3;
InChI key JLTRXTDYQLMHGR-UHFFFAOYSA-N
Quality Level 200 
SMILES string C[Al](C)C
Application: Trimethylaluminum solution can be used as a reagent in the synthesis of:
•  Polyhydroxylated cyclohexanes by stereoselective rearrangement of unsaturated glycosides.
•  Partially hydrolyzed trimethylaluminum (PHT) catalyst for the polymerization of olefins.
•  Methyl benzene by methylation of anisole derivatives using nickel-1,3-dicyclohexylimidazol-2-ylidene catalyst system.
Application: Used in a recently reported Al-catalyzed oxidation based on Oppenauer chemistry providing excellent yields of aldehydes and ketones. As a (1:1) complex with binol catalyzes the dynamic kinetic resolution of secondary alcohols with Novozym 435.
Legal Information: Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Packaging: 1 L in Sure/Seal™
Packaging: 4×25, 100, 800 mL in Sure/Seal™
Packaging: 8, 18 L in Kilo-Lab™
Packaging: The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
Packaging: View returnable container options .
Symbol GHS02GHS05GHS07GHS08  GHS02,GHS05,GHS07,GHS08
Signal word Danger
Hazard statements H225 - H250 - H260 - H304 - H314 - H336 - H361d - H373 - H412
Precautionary statements P210 - P231 + P232 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
Hazard Codes F,C
Risk Statements 63-11-14-17-34-48/20-65-67
Safety Statements 16-26-36/37/39-45-62
RIDADR UN 3399A 4.3(3) / PGI
WGK Germany WGK 2
Flash Point(F) 39.2 °F - closed cup
Flash Point(C) 4 °C - closed cup
Supplemental Hazard Statements EUH014
Density 0.81 g/mL at 25 °C
UNSPSC 12352103

The following items have been added to your cart:

Choose a favorite list for this item:
Catalog Number Description Price
$

Returns/Order support

Please fill out the form below if you want to request order support from Krackeler Scientific.


Quick Order

* Required


New Year Price Updates

We are currently working diligently to update our website pricing information for the New Year. If you place an order, you will be acknowledged with any corrected pricing. If you'd like the most current information sooner, please don't hesitate to drop us an email or give us a call and we'd be happy to assist. Thank you for your patience while we are updating.

800-334-7725
office@krackeler.com


Play Video

To Request a Quote

  1. Search or Browse for items and add to them to your Shopping Cart.
  2. Click the "Request Quote" button at the bottom of the Shopping Cart page.
  3. Fill out required fields.
  4. Optionally you can convert to standard checkout mode by choosing a payment type.
  5. Click "Request Quote" at the bottom of the page.

You will be contacted with a quote.

To Order From a Quote

  1. Register and login to the website.
  2. Receive a quote from your sales representative or customer service.
  3. Have your copy of the quote in hand.
  4. Visit our quote module to search for your quote.
Back to Top