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Tris(triphenylphosphine)rhodium(I) chloride

ALDRICH/199982

Synonym: NSC 124140; RhCl(PPh3)3; Rhodium(I) tris(triphenylphosphine) chloride; Wilkinson’s catalyst

CAS Number: 14694-95-2
Empirical Formula (Hill Notation): C54H45ClP3Rh
Molecular Weight: 925.22
EC Number: 238-744-5
MDL Number: MFCD00010016
Linear Formula: [(C6H5)3P]3RhCl
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-199982-1G 1 g
 $285.00
1/EA		 Add To Favorites
45-199982-5G 5 g
 $1320.00
1/EA		 Add To Favorites

 

InChI 1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key IXAYKDDZKIZSPV-UHFFFAOYSA-M
Quality Level 200 
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
Application: Hydrosilylation Catalysts 

Catalyst used for many organic reactions including:
• Chemoselective allylic alkylations
• Stoichiometric activation of Si-H bonds and hydrosilylations
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst
• Polymerization of diorganostannanes
General description: Tris(triphenylphosphine)rhodium(I) chloride is used as a decarbonylation reagent and as a cocatalyst in Heck reaction.
Packaging: 1, 5 g in glass bottle
UNSPSC 12161600

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