Lanthanum(III) nitrate hexahydrate
ALDRICH/203548 - 99.999% trace metals basis
Synonym: Nitric acid, lanthanum (III) salt, hexahydrate
CAS Number: 10277-43-7
Empirical Formula (Hill Notation): LaN3O9 · 6H2O
Molecular Weight: 433.01
EC Number: 233-238-0
MDL Number: MFCD00149751
Linear Formula: La(NO3)3 · 6H2O
Product Type: Chemical
assay | 99.999% trace metals basis |
form | solid |
impurities | ≤15.0 ppm Trace Rare Earth Analysis |
InChI | 1S/La.3NO3.6H2O/c;3*2-1(3 |
InChI key | GJKFIJKSBFYMQK-UHFFFAOYSA |
mp | 65-68 °C |
Quality Level | 200 |
reaction suitability | reagent type: catalyst core: lanthanum |
SMILES string | [La+3].[H]O[H].[H]O[H].[H |
Application: | Lanthanum(III) nitrate hexahydrate can be used as a catalyst in the synthesis of: • α-aminonitriles by a one-pot three-component coupling of the carbonyl compound, amine, and TMSCN. • Acetals and geminal diacetates (acylals)from aldehydes. • Bis(indolyl) methanes under solvent‐free conditions. It can also be used as a starting material for the electrochemical synthesis of LaMnO3 thin films and solvothermal synthesis of doped lanthanide oxysulfide (La2O2S). |
Features and Benefits: | • Thermal stability • Low toxicity • Mild reaction condition • Chemoselectivity • Low cost |
General description: | Lanthanum(III) nitrate hexahydrate is a transition metal catalyst widely used in many organic transformations such as chemoselective deprotection of acetonides, acetylation of alcohols, phenols, and amines with acetic anhydride, and synthesis of α-amino nitriles. It can also be used as a precursor in the preparation of lanthanum-based nanoparticles. |
Packaging: | 25, 100, 500 g in glass bottle |
Symbol | GHS03,GHS05,GHS09 |
Signal word | Danger |
Hazard statements | H272 - H318 - H410 |
Precautionary statements | P210 - P273 - P280 - P305 + P351 + P338 + P310 |
Hazard Codes | O,Xi |
Risk Statements | 8-36/37/38 |
Safety Statements | 17-26-36 |
RIDADR | UN 1477 5.1 / PGII |
WGK Germany | WGK 3 |
Purity | 99.999% trace metals basis |
mp | 65-68 °C |
UNSPSC | 12352302 |