tert-Butoxy bis(dimethylamino)methane
ALDRICH/20425 - technical
Synonym: Bredereck’s reagent
CAS Number: 5815-08-7
Empirical Formula (Hill Notation): C9H22N2O
Molecular Weight: 174.28
EC Number: 227-383-9
MDL Number: MFCD00042858
Linear Formula: (CH3)3COCH[N(CH3)2]2
Product Type: Chemical
bp | 50-55 °C/15 mmHg (lit.) |
density | 0.844 g/mL at 25 °C (lit.) |
grade | technical |
InChI | 1S/C9H22N2O/c1-9(2,3)12-8 |
InChI key | HXRAMSFGUAOAJR-UHFFFAOYSA |
Quality Level | 200 |
refractive index | n |
n |
|
SMILES string | CN(C)C(OC(C)(C)C)N(C)C |
Analysis Note: | mixture of tert-Butoxy bis(dimethylamino)methane |
Application: | Reactant for: • Preparation of pyrroloquinazolines as photochemotherapeutic agents • Enanatioslective formal synthesis of the Cinchona alkaloid quinine via stereoselective intermolecular radical addition • Synthesis of camptothecin via intramolecular isomuenchnone cycloaddition reaction • Aminomethylenation reactions |
Other Notes: | Review; Mild condensation reactions |
Packaging: | 10, 50 mL in glass bottle |
Symbol | GHS02,GHS07 |
Signal word | Warning |
Hazard statements | H226 - H315 - H319 - H335 |
Precautionary statements | P210 - P302 + P352 - P305 + P351 + P338 |
Hazard Codes | Xi |
Risk Statements | 10-36/37/38 |
Safety Statements | 26 |
RIDADR | UN 1993C 3 / PGIII |
WGK Germany | WGK 3 |
Flash Point(F) | 105.8 °F - closed cup |
Flash Point(C) | 41 °C - closed cup |
bp | 50-55 °C/15 mmHg (lit.) |
Density | 0.844 g/mL at 25 °C (lit.) |
Refractive Index | n |
UNSPSC | 12352100 |