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Tris(triphenylphosphine)rhodium(I) chloride

ALDRICH/205036 - 99.9% trace metals basis

Synonym: NSC 124140; RhCl(PPh3)3; Rhodium(I) tris(triphenylphosphine) chloride; Wilkinson’s catalyst

CAS Number: 14694-95-2
Empirical Formula (Hill Notation): C54H45ClP3Rh
Molecular Weight: 925.22
EC Number: 238-744-5
MDL Number: MFCD00010016
Linear Formula: [(C6H5)3P]3RhCl
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-205036-250MG 250 mg
 $86.10
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45-205036-1G 1 g
 $224.00
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45-205036-5G 5 g
 $604.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material.

This image depicts SKU: 205036-5G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205036-1G

 

assay 99.9% trace metals basis
InChI 1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key IXAYKDDZKIZSPV-UHFFFAOYSA-M
Quality Level 100 
reaction suitability core: rhodium
  reagent type: catalyst
SMILES string Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
Application: Hydrosilylation Catalysts 

Catalyst used for many organic reactions including:
• Chemoselective allylic alkylations
• Stoichiometric activation of Si-H bonds and hydrosilylations
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst
• Polymerization of diorganostannanes
Application: Useful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids. Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.
Packaging: 1 g in glass bottle
Packaging: 250 mg in glass bottle
Packaging: 5 g in poly bottle
Purity 99.9% trace metals basis
UNSPSC 12161600

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