Titanium(IV) isopropoxide
ALDRICH/205273 - 97%
Synonym: TTIP; Tetraisopropyl orthotitanate
CAS Number: 546-68-9
Empirical Formula (Hill Notation): C12H28O4Ti
Molecular Weight: 284.22
EC Number: 208-909-6
MDL Number: MFCD00008871
Linear Formula: Ti[OCH(CH3)2]4
Product Type: Chemical
25 mL Sure/Seal™ Packaging
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205273-100ML.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205273-1L.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205273-500ML.
| assay | 97% |
| bp | 232 °C (lit.) |
| density | 0.96 g/mL at 20 °C (lit.) |
| form | liquid |
| InChI | 1S/4C3H7O.Ti/c4*1-3(2)4;/ |
| InChI key | VXUYXOFXAQZZMF-UHFFFAOYSA |
| mp | 14-17 °C (lit.) |
| Quality Level | 200  |
| reaction suitability | core: titanium |
| reagent type: catalyst | |
| refractive index | n |
| SMILES string | CC(C)O[Ti](OC(C)C)(OC(C)C |
| Application: | Commonly used as a precursor for the preparation of Titania (TiO2) |
| Application: | Novel metal oxide/phosphonate hybrids were formed from titanium(IV) isopropoxide in a two-step sol-gel process. Starting material for barium-strontium-titanate thin films. Used to make porous titanosilicates, potential ion-exchange materials for cleanup of radioactive wastes. Applied in the formation of a heterosupermolecule consisting of a TiO2 nanocrystallite-viologen electron acceptor complex whose light-induced electron transfer has been demonstrated. |
| General description: | Titanium(IV) isopropoxide is a titanium-based coordination compound, commonly used in the asymmetric Sharpless epoxidation reaction of allylic alcohols. It is also used as a catalyst in Kulinkovich reaction for the synthesis of cyclopropanes. |
| Legal Information: | Product of Dorf Ketal |
| Legal Information: | Sure/Seal is a trademark of Sigma-Aldrich Co. LLC |
| Packaging: | 1, 2, 2.5 L in glass bottle |
| Packaging: | 100, 500 mL in glass bottle |
| Packaging: | 4×25 mL in Sure/Seal™ |
| Packaging: | The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product. |
| Symbol |   GHS02,GHS07 |
| Signal word | Warning |
| Hazard statements | H226 - H319 - H336 |
| Precautionary statements | P210 - P233 - P240 - P241 - P242 - P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 10-36-67 |
| Safety Statements | 16-26-36/37/39 |
| RIDADR | UN 2413 3 / PGIII |
| WGK Germany | WGK 1 |
| Flash Point(F) | 105.8 °F - Pensky-Martens c |
| Flash Point(C) | 41 °C - Pensky-Martens clos |
| Purity | 97% |
| bp | 232 °C (lit.) |
| mp | 14-17 °C (lit.) |
| Density | 0.96 g/mL at 20 °C (lit.) |
| Refractive Index | n |
| UNSPSC | 12352106 |