Palladium(II) chloride
ALDRICH/205885 - ReagentPlus®, 99%
Synonym: Dichloropalladium; Palladium dichloride; Palladous chloride
CAS Number: 7647-10-1
Empirical Formula (Hill Notation): Cl2Pd
Molecular Weight: 177.33
EC Number: 231-596-2
MDL Number: MFCD00003558
Linear Formula: Cl2Pd
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205885-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 205885-25G
| assay | 99% |
| density | 4 g/mL at 25 °C (lit.) |
| form | powder |
| InChI | 1S/2ClH.Pd/h2*1H;/q;;+2/p |
| InChI key | PIBWKRNGBLPSSY-UHFFFAOYSA |
| mp | 678-680 °C (lit.) |
| product line | ReagentPlus® |
| Quality Level | 200  |
| reaction suitability | core: palladium |
| reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
| reaction type: Heck Reaction | |
| reaction type: Hiyama Coupling | |
| reaction type: Negishi Coupling | |
| reaction type: Sonogashira Coupling | |
| reaction type: Stille Coupling | |
| reaction type: Suzuki-Miyaura Coupling | |
| reagent type: catalyst | |
| SMILES string | Cl[Pd]Cl |
| Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar. |
| Application: | Palladium(II) chloride (PdCl2) can be used as a catalyst in the following processes: • PdCl2-CuCl2 catalytic system is used in the selective acetylation of 1o and 2o alkyl or aryl alcohols with vinyl acetate to prepare corresponding acetylated derivatives. • PdCl2–EDTA is used in the Suzuki cross-coupling reaction between aryl and heteroaryl halides with aryl(heteroaryl)boronic acids in water. • PdCl2-Cu(OAc)2 is used to synthesize polysubstituted pyrroles from phenethylamines via multiple deprotonations and deamination reactions. • PdCl2-PEG(300) is used in the Suzuki-Miyaura coupling reaction. • PdCl2-NaBH4 is used in the hydrogenation of carbon-carbon triple bonds to synthesize corresponding cis-alkenes in a polyethylene glycol-CH2Cl2 reaction medium. • PdCl2-(n-Bu)3N-NH4OOCH catalytic system is used in the synthesis of benzofurans via intramolecular Heck reaction. For small-scale and high throughput uses, the product is also available as ChemBeads (919853 ) |
| General description: | Palladium(II) chloride is a widely used starting material for preparing other palladium catalysts, reagents, and nanoparticles. |
| Legal Information: | ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany |
| Packaging: | 1, 5, 25, 100 g in glass bottle |
| Symbol |    GHS05,GHS07,GHS09 |
| Signal word | Danger |
| Hazard statements | H290 - H302 - H317 - H318 - H410 |
| Precautionary statements | P234 - P273 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338 |
| Hazard Codes | T |
| Risk Statements | 25-43 |
| Safety Statements | 36/37-45 |
| RIDADR | UN 3288 6.1 / PGIII |
| WGK Germany | WGK 3 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 99% |
| mp | 678-680 °C (lit.) |
| Density | 4 g/mL at 25 °C (lit.) |
| UNSPSC | 12352300 |