Platinum(IV) oxide
ALDRICH/206032
Synonym: Adam’s catalyst; NSC 402624; Platinic oxide; Platinum dioxide
CAS Number: 1314-15-4
Empirical Formula (Hill Notation): O2Pt
Molecular Weight: 227.08
EC Number: 215-223-0
MDL Number: MFCD00011184
Linear Formula: PtO2
Product Type: Chemical
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 206032-50G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 206032-250MG
12 Principles of Green Chemistry: Principle 4—Designing Safer Chemicals
Chemical products should be designed to affect their desired function while minimizing their toxicity.
Chemical products should be designed to affect their desired function while minimizing their toxicity.
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.
| composition | Pt, 81-83% |
| form | solid |
| greener alternative category |  , Aligned |
| greener alternative product characteristics | Designing Safer Chemicals Catalysis Learn more about the Principles of Green Chemistry . |
| InChI | 1S/2O.Pt |
| InChI key | YKIOKAURTKXMSB-UHFFFAOYSA |
| mp | 450 °C (lit.) |
| Quality Level | 200 |
| reaction suitability | core: platinum |
| reagent type: catalyst | |
| SMILES string | O=[Pt]=O |
| surface area | ≥60 m2/g |
| sustainability | Greener Alternative Product |
| Application: | Catalyst for hydrogenation of various functional groups with minimal hydrogenolysis problems; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols. |
| Application: | Catalyst for: • Hydrohydrazination reactions • Oxidation of sugars • Low-temperature oxidation of carbon monoxide • Oxygen reduction reaction • Hydrogenation reactions • Hydrogenolysis of the cyclopropyl group into an isopropyl group • Hydroxycyclopropanation reactions |
| Application: | Platinum(IV) oxide has been used for the reduction of citernyl bromide to form (S)-3,7-dimethyloctylbromid For small scale and high throughput uses, product is also available as ChemBeads (928291 ) |
| General description: | We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here  for more information. |
| Packaging: | 1, 5, 50 g in glass bottle |
| Packaging: | 250 mg in glass bottle |
| Symbol |   GHS03,GHS07 |
| Signal word | Danger |
| Hazard statements | H272 - H319 |
| Precautionary statements | P210 - P305 + P351 + P338 |
| Hazard Codes | O,Xi |
| Risk Statements | 8-36 |
| Safety Statements | 26 |
| RIDADR | UN 1479 5.1 / PGII |
| WGK Germany | WGK 2 |
| mp | 450 °C (lit.) |
| UNSPSC | 12352300 |