Ruthenium(III) chloride
ALDRICH/208523 - Ru content 45-55%
Synonym: Ruthenium trichloride
CAS Number: 10049-08-8
Empirical Formula (Hill Notation): RuCl3
Molecular Weight: 207.43
EC Number: 233-167-5
MDL Number: MFCD00011208
Linear Formula: RuCl3
Product Type: Chemical
density | 3.11 g/mL at 25 °C (lit.) |
form | solid |
InChI | 1S/3ClH.Ru/h3*1H;/q;;;+3/ |
InChI key | YBCAZPLXEGKKFM-UHFFFAOYSA |
reaction suitability | core: ruthenium |
reagent type: catalyst reaction type: Atom Transfer Radical Polymerization (ATRP) |
|
SMILES string | Cl[Ru](Cl)Cl |
Application: | Ruthenium(III) chloride is used as a catalyst: • In the synthesis of β‐amino alcohols by nucleophilic opening of epoxides with anilines. • In the acetylation of varies of phenols, alcohols, thiols, and amines under mild conditions. • In the synthesis of α‐aminonitriles by mixing aldehydes, amines, and trimethylsilyl cyanides. |
General description: | Ruthenium(III) chloride is a chemical compound, that can be used as a mild Lewis acid catalyst for the acetalization of aldehydes, acetalization of alcohols, and conversion of ketoximes to amides. Additionally, it can also be used as a precursor to synthesize Ru nanoparticles. |
Other Notes: | insoluble form |
Packaging: | 2, 10, 50 g in glass bottle |
Symbol | GHS05,GHS07,GHS09 |
Signal word | Danger |
Hazard statements | H302 - H314 - H411 |
Precautionary statements | P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338 |
Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3260 8 / PGII |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
Density | 3.11 g/mL at 25 °C (lit.) |
UNSPSC | 12161600 |