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Bis(triphenylphosphine)palladium(II) dichloride

ALDRICH/208671 - 98%

Synonym: Dichlorobis(triphenylphosphine)palladium(II); Palladium(II)bis(triphenylphosphine) dichloride; PdCl2(PPh3)2

CAS Number: 13965-03-2
Empirical Formula (Hill Notation): C36H30Cl2P2Pd
Molecular Weight: 701.90
EC Number: 237-744-2
MDL Number: MFCD00009593
Linear Formula: [(C6H5)3P]2PdCl2
Product Type: Chemical
Catalog Number PKG Qty. Price Quantity
45-208671-1G 1 g
 $71.00
1/EA		 Add To Favorites
45-208671-5G 5 g
 $221.00
1/EA		 Add To Favorites
45-208671-25G 25 g
 $1040.00
1/EA		 Add To Favorites
45-208671-100G 100 g
 $2300.00
1/EA		 Add To Favorites
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 208671-1G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 208671-100G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 208671-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 208671-1G

 

assay 98%
form solid
InChI 1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
InChI key YNHIGQDRGKUECZ-UHFFFAOYSA-L
reaction suitability core: palladium
  reaction type: Buchwald-Hartwig Cross Coupling Reaction
  reaction type: Heck Reaction
  reaction type: Hiyama Coupling
  reaction type: Negishi Coupling
  reaction type: Sonogashira Coupling
  reaction type: Stille Coupling
  reaction type: Suzuki-Miyaura Coupling
  reagent type: catalyst
SMILES string Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4
Application: Application Guide for Palladium Catalyzed Cross-Coupling Reactions 
Application: Bis(triphenylphosphine)palladium(II) dichloride can be used as a catalyst in the:• Coupling of 2-iodoanisole and terminal alkynes to synthesize 2,3-disubstituted benzofurans.
• Copper-free Sonogashira cross-coupling reaction to synthesize diphenylacetylene.
• Regioselective hydrocarboxylation of styrene.
• Negishi coupling of fluoroarylzinc pivalates to prepare fluorinated oligophenyls.
• Coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins.
For small scale and high throughput uses, product is also available as ChemBeads (927759 )
General description: Bis(triphenylphosphine)palladium(II) dichloride ((PdCl2(PPh3)2) is an organopalladium complex containing tertiary phosphine ligands that is commonly used in C-C bond forming reactions such as Heck arylation, Suzuki coupling, Stille coupling, and Sonogashira coupling.
Packaging: 1, 5, 25, 100 g in glass bottle
Purity 98%
UNSPSC 12161600

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