Palladium(II) acetylacetonate
ALDRICH/209015 - 99%
Synonym: Palladium(II) 2,4-pentanedionate; Pd(acac)2
CAS Number: 14024-61-4
Empirical Formula (Hill Notation): C10H14O4Pd
Molecular Weight: 304.64
EC Number: 237-859-8
MDL Number: MFCD00000025
Linear Formula: Pd(C5H7O2)2
Product Type: Chemical
Pd(acac)2
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 209015-1G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 209015-5G
| assay | 99% |
| form | powder |
| InChI | 1S/2C5H8O2.Pd/c2*1-4(6)3- |
| InChI key | JKDRQYIYVJVOPF-FDGPNNRMSA |
| mp | 200-251 °C (dec.) |
| Quality Level | 100  |
| reaction suitability | core: aluminum |
| reagent type: catalyst | |
| SMILES string | CC(=O)C=C(C)O[Pd]OC(C) |
| Application: | Application Guide for Palladium Catalyzed Cross-Coupling Reactions |
| Application: | Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies: • Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs). • Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides. • As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides. |
| General description: | Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium. |
| Packaging: | 1, 5 g in glass bottle |
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H319 |
| Precautionary statements | P305 + P351 + P338 |
| Hazard Codes | Xi |
| Risk Statements | 36 |
| Safety Statements | 26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | WGK 2 |
| Flash Point(F) | Not applicable |
| Flash Point(C) | Not applicable |
| Purity | 99% |
| mp | 200-251 °C (dec.) |
| UNSPSC | 12352300 |