3-Methoxybenzyl chloride
ALDRICH/209384 - 97%
Synonym: 3-
CAS Number: 824-98-6
Empirical Formula (Hill Notation): C8H9ClO
Molecular Weight: 156.61
MDL Number: MFCD00000907
Linear Formula: CH3OC6H4CH2Cl
Product Type: Chemical
assay | 97% |
bp | 124 °C/13 mmHg (lit.) |
contains | potassium carbonate as stabilizer |
density | 1.078 g/mL |
1.078 g/mL at 25 °C (lit.) | |
form | liquid |
InChI | 1S/C8H9ClO/c1-10-8-4-2-3- |
InChI key | VGISFWWEOGVMED-UHFFFAOYSA |
refractive index | n |
SMILES string | COc1cccc(CCl)c1 |
storage temp. | 2-8°C |
Application: | 3-Methoxybenzyl chloride was used to alkylate 8-benzyloxy-2(1H)-quinolinone in the presence of DMF and NaH. It was also used in the synthesis of diarylmethanes via in situ organozinc-mediated, palladium-catalyzed cross-coupling between benzyl and aryl halide. |
Packaging: | 5, 25 g in glass bottle |
Symbol | GHS05 |
Signal word | Danger |
Hazard statements | H314 |
Precautionary statements | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 |
Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3265 8 / PGII |
WGK Germany | WGK 1 |
Flash Point(F) | 213.8 °F - closed cup |
Flash Point(C) | 101 °C - closed cup |
Purity | 97% |
bp | 124 °C/13 mmHg (lit.) |
Density | 1.078 g/mL at 25 °C (lit.); 1.078 g/mL |
Refractive Index | n |
Storage Temp. | 2-8°C |
UNSPSC | 12352100 |