Palladium hydroxide on carbon
ALDRICH/212911 - extent of labeling: 20 wt. % loading (dry basis), matrix carbon, wet support
Synonym: Pd(OH)2/C; Pearlman’s catalyst
CAS Number: 12135-22-7
Empirical Formula (Hill Notation): H2O2Pd
Molecular Weight: 140.43
EC Number: 235-219-2
MDL Number: MFCD00064599
Linear Formula: H2O2Pd
Product Type: Chemical
contains | ≤50% water |
extent of labeling | 20 wt. % loading (dry basis) |
form | powder |
InChI | 1S/2H2O.Pd/h2*1H2;/q;;+2/ |
InChI key | NXJCBFBQEVOTOW-UHFFFAOYSA |
matrix | carbon, wet support |
Quality Level | 200 |
reaction suitability | core: palladium |
reaction type: Buchwald-Hartwig Cross Coupling Reaction | |
reaction type: Heck Reaction | |
reaction type: Hiyama Coupling | |
reaction type: Negishi Coupling | |
reaction type: Sonogashira Coupling | |
reaction type: Stille Coupling | |
reaction type: Suzuki-Miyaura Coupling | |
reagent type: catalyst | |
SMILES string | O[Pd]O |
Application: | Addition of Pd/C to Pd(OH)2/C improves the efficiency of N- or O-debenzylation. |
Application: | Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes. |
Application: | Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed. Product can be used with our benchtop hydrogen generator, H-Genie Lite (Z744083 ) |
Packaging: | 1, 10, 50, 500 g in glass bottle |
RIDADR | NONH for all modes of transport |
WGK Germany | WGK 3 |
Flash Point(F) | Not applicable |
Flash Point(C) | Not applicable |
UNSPSC | 12352300 |