Potassium triethylborohydride solution

ALDRICH/213438 - 1.0 M in THF

Synonym: Potassium hydrotriethylborate; Potassium triethylhydridoborate

CAS Number: 22560-21-0
Empirical Formula (Hill Notation): C₆H₁₆BK
Molecular Weight: 138.10
MDL Number: MFCD00011702
Linear Formula: KB(C₂H₅)₃H
Product Type: Chemical

Catalog Number	PKG Qty.	Price


45-213438-100ML	100 mL	$173.00 1/EA	Add To Favorites

Properties
Descriptions
Safety Info.
Basic Data

concentration	1.0 M in THF
density	0.902 g/mL at 25 °C
form	liquid
InChI	1S/C6H16B.K/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1
InChI key	MFRDRDKPANBWOI-UHFFFAOYSA-N
Quality Level	100
reaction suitability	reagent type: reductant
SMILES string	[K+].[H][B-](CC)(CC)CC

Application:

• Reducing agent for synthesis of PtNi intermetallic nanoparticle catalysts with electrocatalytic activity
• Reducing agent for preparation of vanadium nanoparticles (~7 nm) stabilized on activated carbon

Reagent for:
• Preparation of lithium, sodium, and potassium boron monohydride complexes with tetramethylethylenediamine and pentamethyldiethylenetriamine
• Dehydrogenation reactions
• Tandem nucleophilic addition/C-C bond cleaving fragmentation reactions with cyclic vinylogous acyl triflates
• Preparation of coordinatively unsaturated pseudotetrahedral iron(II) precursors as precatalysts for the room-temperature hydrogenation of unsaturated hydrocarbons
• Substitution reactions

Packaging:

100 mL in Sure/Seal™

Symbol	GHS02,GHS05,GHS07,GHS08
Signal word	Danger
Hazard statements	H225 - H260 - H302 - H314 - H335 - H351
Precautionary statements	P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
Hazard Codes	F,C
Risk Statements	11-14/15-19-34-37-40
Safety Statements	16-26-36/37/39-43-45
RIDADR	UN 3399A 4.3(3) / PGI
WGK Germany	WGK 3
Flash Point(F)	1.4 °F - closed cup
Flash Point(C)	-17 °C - closed cup
Supplemental Hazard Statements	EUH014 - EUH019

Density	0.902 g/mL at 25 °C
UNSPSC	12352000

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