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TEMPO

ALDRICH/214000 - 98%

Synonym: 2,2,6,6-Tetramethylpiperidine 1-oxyl; 2,2,6,6-Tetramethyl-1-piperidinyloxy, free radical; TEMPO

CAS Number: 2564-83-2
Empirical Formula (Hill Notation): C9H18NO
Molecular Weight: 156.25
EC Number: 219-888-8
MDL Number: MFCD00009599
Linear Formula: C9H18NO
Product Type: Chemical

Catalog Number PKG Qty. Price Quantity
45-214000-1G 1 g
$28.20
1/EA
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45-214000-5G 5 g
$64.10
1/EA
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45-214000-25G 25 g
$176.00
1/EA
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This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 214000-1G.
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 214000-25G
This picture is provided solely for illustration purposes. Optical properties of the actual product may deviate. Relevant product information is printed on labeled products and other accompanying or available information material. This image depicts SKU: 214000-5G
12 Principles of Green Chemistry: Principle 9—Catalytic reagents (as selective as possible) are superior to stoichiometric reagents.

 

assay 98%
form solid
greener alternative category Aligned ,  
greener alternative product characteristics Catalysis
Learn more about the Principles of Green Chemistry .
InChI 1S/C9H18NO/c1-8(2)6-5-7-9(3,4)10(8)11/h5-7H2,1-4H3
InChI key QYTDEUPAUMOIOP-UHFFFAOYSA-N
mp 36-38 °C (lit.)
Quality Level 200 
reaction suitability reagent type: oxidant
SMILES string CC1(C)CCCC(C)(C)N1[O]
storage temp. 2-8°C
sustainability Greener Alternative Product
Application: TEMPO can be used:
• As a catalytic oxidant for copper-catalyzed, greener oxidation of alcohols under aerobic conditions.
• As a catalytic oxidant in the iodobenzene diacetae oxidation of nerol to neral.
• For trapping the styrenyl radical generated from benzoyl peroxide during nitroxide-mediated radical polymerization of styrene.
• In the carboxylation of water-resistant nanofibrillated cellulose (NFC) films.

Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air 
General description: TEMPO (2,2,6,6-Tetramethylpiperidin-1-oxyl) is a stable free radical commonly used as an oxidizing agent in organic synthesis. Copper/TEMPO has been utilized in the catalytic oxidation of primary alcohols to aldehydes.
General description: We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here .
Packaging: 1, 5, 25 g in glass bottle
Purity 98%
mp 36-38 °C (lit.)
Storage Temp. 2-8°C
UNSPSC 12352119

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